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53I126.90

Element 53, a halogen

Iodine

A shiny violet-black solid that turns straight into purple vapor, and the one halogen your body cannot do without.

In nature it is never aloneI₂Read about the molecule

At a glance

Symbol
I
Atomic number
53
Average atomic mass
126.90
Group
17
Period
5
Family
halogen
Electron configuration
[Kr] 4d¹⁰ 5s² 5p⁵
Valence electrons
7
Electronegativity
2.66
Common ions
I⁻ (iodide), as in KI and NaI
Isotopes
¹²⁷I is the only stable one; radioactive ¹³¹I treats thyroid disease and ¹²³I is used for imaging

On the table

Periodic table with Iodine highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 17: the bottom of the 7. The other halogens are tinted, and every cell opens its own article.

Why it pairs up

I

Seven valence electrons, one short of eight. Two iodine atoms share one pair, a single bond, the longest and weakest of the seven.

Properties

State at 25 °C
solid
What it looks like
shiny violet-black crystals made of I₂ molecules
Melting point
113.7 °C
Boiling point
184.4 °C
Density
4.93 g/cm³

Where it is found

The rarest of the stable halogens, about 0.00005% of the crust. Seawater has only 0.05 mg per liter, but seaweed concentrates it thousands of times over. Today most comes from natural brines in Japan and from caliche ore in Chile, where it occurs as iodate.

Discovery and name

Bernard Courtois found it in 1811 in the ash of seaweed he was processing into saltpeter for Napoleon's gunpowder: too much sulfuric acid gave off a violet vapor that condensed into dark crystals. Joseph Gay-Lussac named it from the Greek iodes, violet-colored.

What it is used for

Iodized salt prevents iodine deficiency, iodine solutions and povidone-iodine disinfect skin before surgery, and iodine compounds make X-ray contrast agents, industrial catalysts and cloud-seeding silver iodide. Radioactive iodine-131 treats thyroid disease.

In compounds

KIpotassium iodide, in iodized saltNaIsodium iodideAgIsilver iodide, cloud seedingHIhydroiodic acidC₁₅H₁₁I₄NO₄thyroxine, the thyroid hormoneI₃⁻triiodide, iodine dissolved in iodide