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53I126.90

Element 53, a halogen

Iodine

A shiny violet-black solid that turns straight into purple vapor, and the one halogen your body cannot do without.

In nature it is never aloneI₂Read about the molecule

At a glance

Symbol
I
Atomic number
53
Average atomic mass
126.90
Group
17
Period
5
Family
halogen
Electron configuration
[Kr] 4d¹⁰ 5s² 5p⁵
Valence electrons
7
Electronegativity
2.66
Common ions
I⁻ (iodide), as in KI and NaI
Isotopes
¹²⁷I is the only stable one; radioactive ¹³¹I treats thyroid disease and ¹²³I is used for imaging

On the table

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Period 5, group 17: the bottom of the 7. The other halogens are tinted, and every cell opens its own article.

Electrons and bonding

Iodine has 53 electrons, one for every proton, so the atom carries no charge. Below are the same 53 electrons written two ways.

Simple form: electrons per shell

I
shell 12shell 28shell 318shell 418shell 57
Counting outward from the nucleus: 2, 8, 18, 18, 7. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁵

Short form: [Kr] 4d¹⁰ 5s² 5p⁵, where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s² 4d¹⁰ 5p⁵, because a subshell fills by its energy, not by its shell number.

4d¹⁰↑↓↑↓↑↓↑↓↑↓
5s²↑↓
5p⁵↑↓↑↓↑
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Iodine sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

I

The outer shell holds 7 electrons. Those are the ones iodine can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 17 means 7.

Seven valence electrons, one short of a full shell, so it gains one to form the I⁻ ion or shares one in a covalent bond.

Seven valence electrons, one short of eight. Two iodine atoms share one pair, a single bond, the longest and weakest of the seven.

Properties

State at 25 °C
solid
What it looks like
shiny violet-black crystals made of I₂ molecules
Melting point
113.7 °C
Boiling point
184.4 °C
Density
4.93 g/cm³

Where it is found

The rarest of the stable halogens, about 0.00005% of the crust. Seawater has only 0.05 mg per liter, but seaweed concentrates it thousands of times over. Today most comes from natural brines in Japan and from caliche ore in Chile, where it occurs as iodate.

Discovery and name

Bernard Courtois found it in 1811 in the ash of seaweed he was processing into saltpeter for Napoleon's gunpowder: too much sulfuric acid gave off a violet vapor that condensed into dark crystals. Joseph Gay-Lussac named it from the Greek iodes, violet-colored.

What it is used for

Iodized salt prevents iodine deficiency, iodine solutions and povidone-iodine disinfect skin before surgery, and iodine compounds make X-ray contrast agents, industrial catalysts and cloud-seeding silver iodide. Radioactive iodine-131 treats thyroid disease.

In compounds

KIpotassium iodide, in iodized saltNaIsodium iodideAgIsilver iodide, cloud seedingHIhydroiodic acidC₁₅H₁₁I₄NO₄thyroxine, the thyroid hormoneI₃⁻triiodide, iodine dissolved in iodide