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37Rb85.47

Element 37, an alkali metal

Rubidium

A metal that melts on a hot day, catches fire in air, and keeps time in satellites and cell towers.

At a glance

Symbol
Rb
Atomic number
37
Average atomic mass
85.47
Group
1
Period
5
Family
alkali metal
Electron configuration
[Kr] 5s¹
Valence electrons
1
Electronegativity
0.82
Common ions
Rb⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 1. The other alkali metals are tinted, and every cell opens its own article.

Electrons and bonding

Rubidium has 37 electrons, one for every proton, so the atom carries no charge. Below are the same 37 electrons written two ways.

Simple form: electrons per shell

Rb
shell 12shell 28shell 318shell 48shell 51
Counting outward from the nucleus: 2, 8, 18, 8, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s¹

Short form: [Kr] 5s¹, where [Kr] stands for the 36 electrons krypton already has.

5s¹↑
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Rubidium sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

Rb

The outer shell holds 1 electron. Those are the ones rubidium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 1 means 1.

One valence electron, which rubidium gives up easily to form the Rb⁺ ion. Like the other alkali metals, it reacts with water.

Properties

State at 25 °C
solid
What it looks like
very soft, silvery-white metal
Melting point
39.3 °C
Boiling point
688 °C
Density
1.53 g/cm³
Flame test
red-violet

Where it is found

More abundant in the crust than copper or zinc, but scattered through minerals such as lepidolite and pollucite with no ores of its own. It is recovered as a byproduct of lithium and cesium production.

Discovery and name

Robert Bunsen and Gustav Kirchhoff found it in 1861 with their new spectroscope, in the mineral lepidolite, a year after they found cesium the same way. They named it from the Latin rubidus, deep red, for the color of its brightest spectral lines.

What it is used for

Atomic clocks, including many in GPS satellites and cell towers, and research on ultracold atoms: the first Bose-Einstein condensate, made in 1995, was a cloud of rubidium atoms. It also goes into photocells and specialty glass, and rubidium-strontium dating measures the age of rocks.

In compounds

RbClrubidium chlorideRb₂CO₃rubidium carbonate, in specialty glassRbOHrubidium hydroxide

Handle with care

Catches fire on its own in air and reacts explosively with water, so it is sealed in glass under argon or oil.