All practice pages/Interatomic theory/Elements

97Bk[247]

Element 97, an actinide

Berkelium

Named for Berkeley, and a rare starting material for making even heavier elements.

At a glance

Symbol
Bk
Atomic number
97
Mass number of its longest-lived isotope
[247]
Group
none; it sits in the actinide row below the table
Period
7
Family
actinide
Electron configuration
[Rn] 5f⁹ 7s²
Electronegativity
1.30
Common ions
Bk³⁺ and Bk⁴⁺
Isotopes
none are stable; ²⁴⁷Bk lasts longest, about 1,400 years

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 7, in the actinide row set below the main table. The other actinides are tinted, and every cell opens its own article.

Electrons and bonding

Berkelium has 97 electrons, one for every proton, so the atom carries no charge. Below are the same 97 electrons written two ways.

Simple form: electrons per shell

Bk
shell 12shell 28shell 318shell 432shell 527shell 68shell 72
Counting outward from the nucleus: 2, 8, 18, 32, 27, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 5f⁹ 6s² 6p⁶ 7s²

Short form: [Rn] 5f⁹ 7s², where [Rn] stands for the 86 electrons radon already has.

That list runs by shell. In the order the subshells fill it reads [Rn] 7s² 5f⁹, because a subshell fills by its energy, not by its shell number.

5f⁹↑↓↑↓↑↑↑↑↑
7s²↑↓
The boxes hold the electrons beyond [Rn]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Berkelium sits in period 7 and has 7 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones berkelium can lose, gain or share, so they are the ones that decide what it bonds with.

Radioactive, like every actinide. It gives up electrons to form positive ions.

Properties

State at 25 °C
solid
What it looks like
silvery, radioactive metal
Melting point
1050 °C
Boiling point
not known
Density
14.8 g/cm³

Where it is found

Not found in nature; made in minute amounts in high-flux reactors such as the one at Oak Ridge, Tennessee.

Discovery and name

Stanley Thompson, Albert Ghiorso and Glenn Seaborg made it in December 1949 at Berkeley by bombarding americium with alpha particles, and named it after the city.

What it is used for

Research only. In 2009, 22 milligrams of berkelium-249 made at Oak Ridge were flown to Russia and bombarded to make tennessine.

In compounds

BkO₂berkelium dioxideBkCl₃berkelium chloride

Handle with care

Radioactive, and only ever available in milligram amounts.