All practice pages/Interatomic theory/Elements

64Gd157.25

Element 64, a lanthanide

Gadolinium

The metal that makes MRI scans sharper, and one that turns magnetic on a cold day.

At a glance

Symbol
Gd
Atomic number
64
Average atomic mass
157.25
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f⁷ 5d¹ 6s²
Electronegativity
1.20
Common ions
Gd³⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Gadolinium has 64 electrons, one for every proton, so the atom carries no charge. Below are the same 64 electrons written two ways.

Simple form: electrons per shell

Gd
shell 12shell 28shell 318shell 425shell 59shell 62
Counting outward from the nucleus: 2, 8, 18, 25, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁷ 5s² 5p⁶ 5d¹ 6s²

Short form: [Xe] 4f⁷ 5d¹ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f⁷ 5d¹, because a subshell fills by its energy, not by its shell number.

4f⁷↑↑↑↑↑↑↑
5d¹↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f⁷, and 2 + 6 + 10 + 7 is 25.

Gadolinium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones gadolinium can lose, gain or share, so they are the ones that decide what it bonds with.

Gadolinium gives up three electrons to form Gd³⁺, which keeps seven unpaired f electrons. Those unpaired electrons make it strongly magnetic, the property MRI contrast agents rely on.

Properties

State at 25 °C
solid
What it looks like
silvery-white metal
Melting point
1313 °C
Boiling point
3273 °C
Density
7.90 g/cm³
Magnetic
yes, below about 20 °C, so a chilled piece is attracted to a magnet and a warm one barely is

Where it is found

Found in monazite and bastnäsite, mostly mined in China.

Discovery and name

Jean Charles Galissard de Marignac detected it in 1880, and Paul-Émile Lecoq de Boisbaudran separated its oxide in 1886. It was named after the mineral gadolinite, which honors Johan Gadolin, the Finnish chemist who first analyzed ore from Ytterby.

What it is used for

Gadolinium compounds injected before an MRI scan make blood vessels and tumors stand out. Gadolinium absorbs neutrons better than any other stable element, so it helps control some nuclear reactors, and it goes into phosphors, magnetic refrigeration research and data storage.

In compounds

Gd₂O₃gadolinium oxideGdCl₃gadolinium chlorideGd₃Ga₅O₁₂gadolinium gallium garnet