All practice pages/Interatomic theory/Elements

50Sn118.71

Element 50, a post-transition metal

Tin

The metal that turned copper into bronze and started an age, and the solder that holds electronics together.

At a glance

Symbol
Sn
Atomic number
50
Average atomic mass
118.71
Group
14
Period
5
Family
post-transition metal
Electron configuration
[Kr] 4d¹⁰ 5s² 5p²
Valence electrons
4
Electronegativity
1.96
Common ions
Sn²⁺ and Sn⁴⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 14. The other post-transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Tin has 50 electrons, one for every proton, so the atom carries no charge. Below are the same 50 electrons written two ways.

Simple form: electrons per shell

Sn
shell 12shell 28shell 318shell 418shell 54
Counting outward from the nucleus: 2, 8, 18, 18, 4. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p²

Short form: [Kr] 4d¹⁰ 5s² 5p², where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s² 4d¹⁰ 5p², because a subshell fills by its energy, not by its shell number.

4d¹⁰↑↓↑↓↑↓↑↓↑↓
5s²↑↓
5p²↑↑
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Tin sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

Sn

The outer shell holds 4 electrons. Those are the ones tin can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 14 means 4.

Four valence electrons. Tin forms Sn²⁺ or Sn⁴⁺ ions, and also shares electrons in covalent compounds such as tin(IV) chloride.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-white metal
Melting point
231.9 °C
Boiling point
2602 °C
Density
7.29 g/cm³
Odd fact
below 13 °C, white tin can slowly crumble into gray powder, a change called tin pest

Where it is found

Mined almost entirely as cassiterite (SnO₂), mainly in China, Indonesia, Myanmar and Peru. Cornwall in England was a major source from the Bronze Age into the 1900s.

Discovery and name

Known since ancient times; adding tin to copper made bronze and began the Bronze Age more than 5,000 years ago. The name is Old English, and the symbol Sn comes from its Latin name stannum.

What it is used for

Solder for electronics takes about half. Tin also coats the steel of food cans, which is why they are called tin cans, and makes bronze, pewter and organ pipes. Molten tin is the flat bed on which window glass is floated, and tin compounds stabilize PVC plastic.

In compounds

SnO₂tin(IV) oxide, cassiteriteSnCl₂tin(II) chlorideSnF₂tin(II) fluoride, in toothpasteSnCl₄tin(IV) chloride