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57La138.91

Element 57, a lanthanide

Lanthanum

The first of the lanthanides, the row of look-alike metals that takes its name, and a working part of many hybrid car batteries.

At a glance

Symbol
La
Atomic number
57
Average atomic mass
138.91
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 5d¹ 6s²
Electronegativity
1.10
Common ions
La³⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Lanthanum has 57 electrons, one for every proton, so the atom carries no charge. Below are the same 57 electrons written two ways.

Simple form: electrons per shell

La
shell 12shell 28shell 318shell 418shell 59shell 62
Counting outward from the nucleus: 2, 8, 18, 18, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 5d¹ 6s²

Short form: [Xe] 5d¹ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 5d¹, because a subshell fills by its energy, not by its shell number.

5d¹↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Lanthanum sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones lanthanum can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the La³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-white metal that tarnishes in air
Melting point
918 °C
Boiling point
3464 °C
Density
6.15 g/cm³

Where it is found

Found with the other rare earths in monazite and bastnäsite, mined mostly in China, the United States, Australia and Myanmar.

Discovery and name

Carl Gustaf Mosander found it in 1839 hidden in cerium nitrate, which he had thought was pure. He named it from the Greek lanthanein, to lie hidden.

What it is used for

Nickel-metal hydride batteries in hybrid cars contain kilograms of a lanthanum-rich alloy. Lanthanum oxide makes high-quality camera and telescope lenses, lanthanum catalysts crack crude oil into gasoline, and lanthanum carbonate is a medicine that controls phosphate levels in kidney patients.

In compounds

La₂O₃lanthanum oxide, in lens glassLaNi₅lanthanum nickel, stores hydrogenLa₂(CO₃)₃lanthanum carbonate, a medicineLaB₆lanthanum hexaboride, electron sources