All practice pages/Interatomic theory/Elements

22Ti47.87

Element 22, a transition metal

Titanium

As strong as many steels at about half the weight, and so friendly to the body that bone grows right onto it.

At a glance

Symbol
Ti
Atomic number
22
Average atomic mass
47.87
Group
4
Period
4
Family
transition metal
Electron configuration
[Ar] 3d² 4s²
Electronegativity
1.54
Common ions
Ti⁴⁺ in most compounds; also +3 and +2

On the table

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Period 4, group 4. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Titanium has 22 electrons, one for every proton, so the atom carries no charge. Below are the same 22 electrons written two ways.

Simple form: electrons per shell

Ti
shell 12shell 28shell 310shell 42
Counting outward from the nucleus: 2, 8, 10, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d² 4s²

Short form: [Ar] 3d² 4s², where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s² 3d², because a subshell fills by its energy, not by its shell number.

3d²↑↑
4s²↑↓
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d², and 2 + 6 + 2 is 10.

Titanium sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones titanium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, titanium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
shiny, silver-gray metal
Melting point
1668 °C
Boiling point
3287 °C
Density
4.5 g/cm³

Where it is found

The ninth most abundant element in the crust, in the minerals ilmenite (FeTiO₃) and rutile (TiO₂) found in beach sands and igneous rock. Australia, South Africa and China mine the most.

Discovery and name

William Gregor, a clergyman in Cornwall, found an unknown metal in black sand in 1791. Martin Heinrich Klaproth found it again in rutile in 1795 and named it after the Titans of Greek myth. Pure titanium metal was not made until 1910, and the Kroll process that produces it commercially came in the 1940s.

What it is used for

About 95% of titanium ore becomes titanium dioxide, the brilliant white pigment in paint, paper, plastics, toothpaste and sunscreen. The metal goes into jet engines and airframes, hip and knee replacements, dental implants, eyeglass frames and bike frames, and it clads buildings such as the Guggenheim Museum in Bilbao.

In compounds

TiO₂titanium dioxide, white pigmentTiCl₄titanium tetrachloride, makes smoke screensFeTiO₃ilmeniteTiCtitanium carbide, cutting toolsTiNtitanium nitride, gold-colored coatings