All practice pages/Interatomic theory/Elements

98Cf[251]

Element 98, an actinide

Californium

Named for California, and a powerful source of neutrons that can start up reactors and find gold.

At a glance

Symbol
Cf
Atomic number
98
Mass number of its longest-lived isotope
[251]
Group
none; it sits in the actinide row below the table
Period
7
Family
actinide
Electron configuration
[Rn] 5f¹⁰ 7s²
Electronegativity
1.30
Common ions
Cf³⁺
Isotopes
none are stable; ²⁵¹Cf lasts longest, about 900 years; ²⁵²Cf, with a half-life of 2.6 years, is the useful one

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 7, in the actinide row set below the main table. The other actinides are tinted, and every cell opens its own article.

Electrons and bonding

Californium has 98 electrons, one for every proton, so the atom carries no charge. Below are the same 98 electrons written two ways.

Simple form: electrons per shell

Cf
shell 12shell 28shell 318shell 432shell 528shell 68shell 72
Counting outward from the nucleus: 2, 8, 18, 32, 28, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 5f¹⁰ 6s² 6p⁶ 7s²

Short form: [Rn] 5f¹⁰ 7s², where [Rn] stands for the 86 electrons radon already has.

That list runs by shell. In the order the subshells fill it reads [Rn] 7s² 5f¹⁰, because a subshell fills by its energy, not by its shell number.

5f¹⁰↑↓↑↓↑↓↑↑↑↑
7s²↑↓
The boxes hold the electrons beyond [Rn]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Californium sits in period 7 and has 7 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones californium can lose, gain or share, so they are the ones that decide what it bonds with.

Radioactive, like every actinide. It gives up electrons to form positive ions.

Properties

State at 25 °C
solid
What it looks like
silvery, radioactive metal
Melting point
900 °C
Boiling point
not known
Density
not measured

Where it is found

Not found in nature; made in small amounts in high-flux reactors.

Discovery and name

Stanley Thompson, Kenneth Street Jr., Albert Ghiorso and Glenn Seaborg made it in 1950 at Berkeley by bombarding curium with alpha particles, and named it after the state and its university.

What it is used for

Californium-252 splits on its own and releases neutrons, so a few micrograms can start up nuclear reactors, measure water and oil in rock, find gold and silver ores, scan luggage for explosives, and treat some cancers. Californium-249 was the target used to make oganesson.

In compounds

Cf₂O₃californium(III) oxideCfCl₃californium chloride

Handle with care

An intense neutron source; even micrograms need heavy shielding.