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17Cl35.45

Element 17, a halogen

Chlorine

The halogen of table salt, bleach and swimming pools: a greenish, choking gas as an element, and a harmless ion in the sea.

In nature it is never aloneCl₂Read about the molecule

At a glance

Symbol
Cl
Atomic number
17
Average atomic mass
35.45
Group
17
Period
3
Family
halogen
Electron configuration
1s² 2s² 2p⁶ 3s² 3p⁵, or [Ne] 3s² 3p⁵
Valence electrons
7
Electronegativity
3.16
Common ions
Cl⁻ (chloride), as in NaCl and HCl
Isotopes
³⁵Cl (75.8%) and ³⁷Cl (24.2%), which is why the average mass is 35.45 and not a whole number

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 3, group 17: the second rung down the stem of the 7. The other halogens are tinted, and every cell opens its own article.

Electrons and bonding

Chlorine has 17 electrons, one for every proton, so the atom carries no charge. Below are the same 17 electrons written two ways.

Simple form: electrons per shell

Cl
shell 12shell 28shell 37
Counting outward from the nucleus: 2, 8, 7. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁵

Short form: [Ne] 3s² 3p⁵, where [Ne] stands for the 10 electrons neon already has.

3s²↑↓
3p⁵↑↓↑↓↑
The boxes hold the electrons beyond [Ne]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p⁶, and 2 + 6 is 8.

Chlorine sits in period 3 and has 3 shells. The period number counts the shells.

What that means for bonding

Cl

The outer shell holds 7 electrons. Those are the ones chlorine can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 17 means 7.

Seven valence electrons, one short of a full shell, so it gains one to form the Cl⁻ ion or shares one in a covalent bond.

Seven valence electrons, one short of eight. Two chlorine atoms share one pair, a single bond.

Properties

State at 25 °C
gas
What it looks like
yellow-green gas made of Cl₂ molecules
Melting point
−101.5 °C
Boiling point
−34.0 °C
Density
3.21 g/L at 0 °C and 1 atm

Where it is found

About 1.9% of seawater by mass is chloride, and beds of rock salt (halite, NaCl) mark the places where ancient seas dried up. It is about 0.015% of the crust, and never free in nature.

Discovery and name

Scheele made the gas in 1774 from hydrochloric acid and manganese dioxide, but thought it contained oxygen. Humphry Davy showed in 1810 that it was an element and named it from the Greek chloros, pale green.

What it is used for

Chlorine gas disinfects drinking water and pools and makes bleach. Chlorine compounds make PVC pipe and flooring, solvents, pesticides and many medicines, and the chloride in table salt is essential to life.

In compounds

NaClsodium chloride, table saltHClhydrochloric acid, stomach acidNaOClsodium hypochlorite, bleachCaCl₂calcium chloride, road salt(C₂H₃Cl)ₙPVC plasticCHCl₃chloroform