All practice pages/Interatomic theory/Elements

91Pa231.04

Element 91, an actinide

Protactinium

A rare, highly radioactive metal whose name means before actinium, the element it decays into.

At a glance

Symbol
Pa
Atomic number
91
Average atomic mass
231.04
Group
none; it sits in the actinide row below the table
Period
7
Family
actinide
Electron configuration
[Rn] 5f² 6d¹ 7s²
Electronegativity
1.50
Common ions
+5 most commonly; also +4
Isotopes
none are stable; ²³¹Pa, with a half-life of about 33,000 years, is the longest-lived

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 7, in the actinide row set below the main table. The other actinides are tinted, and every cell opens its own article.

Electrons and bonding

Protactinium has 91 electrons, one for every proton, so the atom carries no charge. Below are the same 91 electrons written two ways.

Simple form: electrons per shell

Pa
shell 12shell 28shell 318shell 432shell 520shell 69shell 72
Counting outward from the nucleus: 2, 8, 18, 32, 20, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 5f² 6s² 6p⁶ 6d¹ 7s²

Short form: [Rn] 5f² 6d¹ 7s², where [Rn] stands for the 86 electrons radon already has.

That list runs by shell. In the order the subshells fill it reads [Rn] 7s² 5f² 6d¹, because a subshell fills by its energy, not by its shell number.

5f²↑↑
6d¹↑
7s²↑↓
The boxes hold the electrons beyond [Rn]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Protactinium sits in period 7 and has 7 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones protactinium can lose, gain or share, so they are the ones that decide what it bonds with.

Radioactive, like every actinide. It gives up electrons to form positive ions.

Properties

State at 25 °C
solid
What it looks like
bright, silvery, radioactive metal
Melting point
1572 °C
Boiling point
not known
Density
15.4 g/cm³

Where it is found

One of the rarest natural elements, present in uranium ores at about a third of a gram per ton of uranium.

Discovery and name

Kasimir Fajans and Oswald Göhring found a short-lived isotope in 1913 and called it brevium. In 1917 and 1918 Otto Hahn and Lise Meitner, and separately Frederick Soddy and John Cranston, found the long-lived isotope. It was named protoactinium, before actinium, which was shortened to protactinium in 1949.

What it is used for

None outside research. The ratio of protactinium-231 to thorium-230 in ocean sediments helps date them and trace ocean currents of the past.

In compounds

Pa₂O₅protactinium pentoxidePaCl₅protactinium pentachloride

Handle with care

Highly radioactive and toxic.