All practice pages/Interatomic theory/Elements

90Th232.04

Element 90, an actinide

Thorium

Named after the Norse god of thunder, far more abundant than uranium, and a possible fuel for future nuclear reactors.

At a glance

Symbol
Th
Atomic number
90
Average atomic mass
232.04
Group
none; it sits in the actinide row below the table
Period
7
Family
actinide
Electron configuration
[Rn] 6d² 7s²
Electronegativity
1.30
Common ions
Th⁴⁺
Isotopes
²³²Th, weakly radioactive, with a half-life of 14 billion years, about the age of the universe

On the table

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Period 7, in the actinide row set below the main table. The other actinides are tinted, and every cell opens its own article.

Electrons and bonding

Thorium has 90 electrons, one for every proton, so the atom carries no charge. Below are the same 90 electrons written two ways.

Simple form: electrons per shell

Th
shell 12shell 28shell 318shell 432shell 518shell 610shell 72
Counting outward from the nucleus: 2, 8, 18, 32, 18, 10, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶ 6d² 7s²

Short form: [Rn] 6d² 7s², where [Rn] stands for the 86 electrons radon already has.

That list runs by shell. In the order the subshells fill it reads [Rn] 7s² 6d², because a subshell fills by its energy, not by its shell number.

6d²↑↑
7s²↑↓
The boxes hold the electrons beyond [Rn]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Thorium sits in period 7 and has 7 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones thorium can lose, gain or share, so they are the ones that decide what it bonds with.

Radioactive, like every actinide. It gives up electrons to form positive ions.

Properties

State at 25 °C
solid
What it looks like
silvery metal that tarnishes to black in air
Melting point
1750 °C
Boiling point
4788 °C
Density
11.7 g/cm³

Where it is found

About three times as abundant in the crust as uranium, found mostly in monazite sands in India, Brazil and elsewhere.

Discovery and name

Jöns Jacob Berzelius identified it in 1829 in a black mineral from Norway sent to him by Morten Thrane Esmark, and named it after Thor. In 1898 Marie Curie and Gerhard Carl Schmidt each found that it was radioactive.

What it is used for

Thorium oxide once made gas lantern mantles glow brightly and still goes into heat-resistant ceramics, and thoriated tungsten makes welding electrodes. In a reactor thorium can be turned into uranium-233 fuel, and thorium reactors are being developed in India and China.

In compounds

ThO₂thorium dioxide, a very high-melting oxideThF₄thorium fluorideThSiO₄thorite

Handle with care

Weakly radioactive, and its dust is dangerous to inhale. Old camping lantern mantles and some vintage camera lenses contain thorium.