All practice pages/Interatomic theory/Elements

83Bi208.98

Element 83, a post-transition metal

Bismuth

A heavy metal gentle enough to swallow in a stomach remedy, and one that grows rainbow-colored staircase crystals.

At a glance

Symbol
Bi
Atomic number
83
Average atomic mass
208.98
Group
15
Period
6
Family
post-transition metal
Electron configuration
[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³
Valence electrons
5
Electronegativity
2.02
Common ions
Bi³⁺
Isotopes
²⁰⁹Bi, long thought stable, is very slightly radioactive: its half-life, measured in 2003, is about 2 × 10¹⁹ years, a billion times the age of the universe

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, group 15. The other post-transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Bismuth has 83 electrons, one for every proton, so the atom carries no charge. Below are the same 83 electrons written two ways.

Simple form: electrons per shell

Bi
shell 12shell 28shell 318shell 432shell 518shell 65
Counting outward from the nucleus: 2, 8, 18, 32, 18, 5. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p³

Short form: [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³, where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹⁴ 5d¹⁰ 6p³, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d¹⁰↑↓↑↓↑↓↑↓↑↓
6s²↑↓
6p³↑↑↑
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Bismuth sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

Bi

The outer shell holds 5 electrons. Those are the ones bismuth can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 15 means 5.

A metal that gives up its valence electrons to form positive ions, though less readily than the metals to its left.

Properties

State at 25 °C
solid
What it looks like
brittle, silvery-white metal with a pink tint; its crystals shimmer with rainbow colors from a thin oxide layer
Melting point
271.4 °C
Boiling point
1564 °C
Density
9.81 g/cm³
Odd fact
it expands when it freezes, and it is the element most strongly pushed away by a magnet

Where it is found

Rare, and mostly recovered as a byproduct of refining lead, copper and tungsten ores, above all in China.

Discovery and name

Known since the 1400s but often confused with tin and lead, until Claude François Geoffroy showed in 1753 that it was a separate element. The name probably comes from the old German wismuth, perhaps from weisse Masse, white mass.

What it is used for

Stomach medicines such as bismuth subsalicylate, the pink remedy. It replaces toxic lead in solder, plumbing brass, fishing weights and shotgun pellets, and low-melting bismuth alloys trigger fire sprinklers and fuses. Bismuth oxychloride gives cosmetics a pearly shine.

In compounds

Bi₂O₃bismuth oxideBiOClbismuth oxychloride, pearly cosmeticsC₇H₅BiO₄bismuth subsalicylate, a stomach remedyBi₂Te₃bismuth telluride