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54Xe131.29

Element 54, a noble gas

Xenon

A heavy noble gas that proved noble gases can react, now lighting car headlights and pushing spacecraft through space.

At a glance

Symbol
Xe
Atomic number
54
Average atomic mass
131.29
Group
18
Period
5
Family
noble gas
Electron configuration
[Kr] 4d¹⁰ 5s² 5p⁶
Valence electrons
8
Electronegativity
2.60

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 18. The other noble gases are tinted, and every cell opens its own article.

Electrons and bonding

Xenon has 54 electrons, one for every proton, so the atom carries no charge. Below are the same 54 electrons written two ways.

Simple form: electrons per shell

Xe
shell 12shell 28shell 318shell 418shell 58
Counting outward from the nucleus: 2, 8, 18, 18, 8. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶

Short form: [Kr] 4d¹⁰ 5s² 5p⁶, where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s² 4d¹⁰ 5p⁶, because a subshell fills by its energy, not by its shell number.

4d¹⁰↑↓↑↓↑↓↑↓↑↓
5s²↑↓
5p⁶↑↓↑↓↑↓
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Xenon sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

Xe

The outer shell holds 8 electrons. Those are the ones xenon can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 18 means 8.

A full valence shell, but its outer electrons sit far from the nucleus, so xenon can be forced to share them with fluorine and oxygen. It forms more compounds than any other noble gas.

Properties

State at 25 °C
gas
What it looks like
colorless, odorless, very dense gas
Melting point
−111.8 °C
Boiling point
−108.1 °C
Density
5.89 g/L at 0 °C and 1 atm

Where it is found

About 0.09 parts per million of air, one of the rarest gases in the atmosphere, collected when air is liquefied and separated.

Discovery and name

William Ramsay and Morris Travers found it in July 1898 in the residue of evaporated liquid air and named it from the Greek xenos, stranger. In 1962 Neil Bartlett made xenon hexafluoroplatinate, the first compound of a noble gas, overturning the belief that noble gases could not react.

What it is used for

Bright xenon lamps in car headlights, cinema projectors and camera flashes; ion thrusters on spacecraft such as NASA's Dawn probe; a general anesthetic; and large tanks of liquid xenon in underground detectors searching for dark matter.

In compounds

XeF₂xenon difluorideXeF₄xenon tetrafluorideXeF₆xenon hexafluorideXeO₃xenon trioxide, explosive