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11Na22.99

Element 11, an alkali metal

Sodium

A metal soft enough to cut with a butter knife that fizzes and flares on water, and one of the two elements in table salt.

At a glance

Symbol
Na
Atomic number
11
Average atomic mass
22.99
Group
1
Period
3
Family
alkali metal
Electron configuration
1s² 2s² 2p⁶ 3s¹, or [Ne] 3s¹
Valence electrons
1
Electronegativity
0.93
Common ions
Na⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 3, group 1. The other alkali metals are tinted, and every cell opens its own article.

Electrons and bonding

Sodium has 11 electrons, one for every proton, so the atom carries no charge. Below are the same 11 electrons written two ways.

Simple form: electrons per shell

Na
shell 12shell 28shell 31
Counting outward from the nucleus: 2, 8, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s¹

Short form: [Ne] 3s¹, where [Ne] stands for the 10 electrons neon already has.

3s¹↑
The boxes hold the electrons beyond [Ne]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p⁶, and 2 + 6 is 8.

Sodium sits in period 3 and has 3 shells. The period number counts the shells.

What that means for bonding

Na

The outer shell holds 1 electron. Those are the ones sodium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 1 means 1.

One valence electron, which sodium gives up easily to form the Na⁺ ion. Like the other alkali metals, it reacts with water.

Properties

State at 25 °C
solid
What it looks like
soft, silvery metal that tarnishes within seconds in air
Melting point
97.8 °C
Boiling point
883 °C
Density
0.97 g/cm³
Flame test
bright yellow-orange

Where it is found

The sixth most abundant element in the crust, about 2.4% by mass, always combined: in beds of rock salt, in feldspar minerals, and dissolved in the ocean, where sodium chloride makes up most of the salt. Every cell in your body depends on Na⁺ ions to carry nerve signals.

Discovery and name

Humphry Davy isolated it in 1807 by passing electricity through molten sodium hydroxide, days after doing the same for potassium. The name comes from soda. The symbol Na comes from its Latin name natrium, after natron, a natural soda the ancient Egyptians used in mummification.

What it is used for

Sodium chloride seasons and preserves food, melts ice on roads, and is the starting point for making chlorine and sodium hydroxide. Sodium bicarbonate is baking soda. The metal itself lights orange-yellow street lamps, cools some nuclear reactors as a liquid, and helps extract titanium from its ore.

In compounds

NaClsodium chloride, table saltNaHCO₃sodium bicarbonate, baking sodaNaOHsodium hydroxide, lyeNa₂CO₃sodium carbonate, washing sodaNaOClsodium hypochlorite, bleachNaFsodium fluoride, in toothpaste

Handle with care

The metal reacts violently with water, releasing hydrogen that can ignite, so it is stored under oil. Sodium hydroxide is strongly corrosive to skin and eyes.