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78Pt195.08

Element 78, a transition metal

Platinum

A precious metal rarer than gold, the catalyst that cleans diesel exhaust, and the core of a widely used cancer drug.

At a glance

Symbol
Pt
Atomic number
78
Average atomic mass
195.08
Group
10
Period
6
Family
transition metal
Electron configuration
[Xe] 4f¹⁴ 5d⁹ 6s¹
Electronegativity
2.28
Common ions
+2 and +4

On the table

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Period 6, group 10. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Platinum has 78 electrons, one for every proton, so the atom carries no charge. Below are the same 78 electrons written two ways.

Simple form: electrons per shell

Pt
shell 12shell 28shell 318shell 432shell 517shell 61
Counting outward from the nucleus: 2, 8, 18, 32, 17, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d⁹ 6s¹

Short form: [Xe] 4f¹⁴ 5d⁹ 6s¹, where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s¹ 4f¹⁴ 5d⁹, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d⁹↑↓↑↓↑↓↑↓↑
6s¹↑
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Platinum sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones platinum can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, platinum loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
dense, silvery-white metal that never tarnishes
Melting point
1768.4 °C
Boiling point
3825 °C
Density
21.5 g/cm³

Where it is found

Found as native grains and in nickel-copper ores. South Africa's Bushveld Complex supplies about 70% of the world's platinum, with Russia next.

Discovery and name

Peoples of pre-Columbian South America worked it into jewelry. Spanish colonists dismissed it as platina, little silver, an annoying impurity in gold, and Antonio de Ulloa described it scientifically in 1748. Its name comes from that Spanish word.

What it is used for

Catalytic converters, especially for diesel vehicles, take the largest share, followed by jewelry and investment bars. Platinum catalysts make nitric acid and refine gasoline, platinum electrodes serve in fuel cells and labs, and cisplatin, a platinum compound, has treated testicular, ovarian and other cancers since the 1970s.

In compounds

Pt(NH₃)₂Cl₂cisplatin, a cancer drugPtO₂platinum dioxide, a catalystH₂PtCl₆hexachloroplatinic acidPtCl₂platinum(II) chloride