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75Re186.21

Element 75, a transition metal

Rhenium

The last stable element to be discovered and one of the rarest, now working in the hottest parts of jet engines.

At a glance

Symbol
Re
Atomic number
75
Average atomic mass
186.21
Group
7
Period
6
Family
transition metal
Electron configuration
[Xe] 4f¹⁴ 5d⁵ 6s²
Electronegativity
1.90
Common ions
+7 in the perrhenate ion ReO₄⁻; also +4 and +6

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, group 7. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Rhenium has 75 electrons, one for every proton, so the atom carries no charge. Below are the same 75 electrons written two ways.

Simple form: electrons per shell

Re
shell 12shell 28shell 318shell 432shell 513shell 62
Counting outward from the nucleus: 2, 8, 18, 32, 13, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d⁵ 6s²

Short form: [Xe] 4f¹⁴ 5d⁵ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹⁴ 5d⁵, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d⁵↑↑↑↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Rhenium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones rhenium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, rhenium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
dense, silvery-white metal
Melting point
3186 °C
Boiling point
5596 °C
Density
20.8 g/cm³

Where it is found

One of the rarest elements in the crust. It is recovered from the molybdenite in copper ores, mainly in Chile and the United States.

Discovery and name

Walter Noddack, Ida Tacke and Otto Berg found it in Germany in 1925, detecting it by its X-ray spectrum in platinum ore and columbite, and named it after the Rhine. Ida Tacke, later Ida Noddack, was also the first to suggest, in 1934, that heavy nuclei could split, years before fission was discovered.

What it is used for

Nearly all goes into nickel superalloys for jet engine turbine blades, which must stay strong close to their melting point. Platinum-rhenium catalysts help refine high-octane gasoline, and rhenium makes thermocouples and filaments for mass spectrometers.

In compounds

Re₂O₇rhenium heptoxideNH₄ReO₄ammonium perrhenateReS₂rhenium disulfideReO₃rhenium trioxide, conducts like a metal