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65Tb158.93

Element 65, a lanthanide

Terbium

A rare earth from the Ytterby quarry whose compounds glow a vivid green.

At a glance

Symbol
Tb
Atomic number
65
Average atomic mass
158.93
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f⁹ 6s²
Electronegativity
not measured
Common ions
Tb³⁺, and also Tb⁴⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Terbium has 65 electrons, one for every proton, so the atom carries no charge. Below are the same 65 electrons written two ways.

Simple form: electrons per shell

Tb
shell 12shell 28shell 318shell 427shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 27, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁹ 5s² 5p⁶ 6s²

Short form: [Xe] 4f⁹ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f⁹, because a subshell fills by its energy, not by its shell number.

4f⁹↑↓↑↓↑↑↑↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f⁹, and 2 + 6 + 10 + 9 is 27.

Terbium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones terbium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Tb³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-gray metal
Melting point
1356 °C
Boiling point
3230 °C
Density
8.23 g/cm³

Where it is found

One of the rarer rare earths, found in xenotime, monazite and the ion-adsorption clays of southern China.

Discovery and name

Carl Gustaf Mosander found it in 1843 in yttria from Ytterby, together with erbium, and both were named after the village. The two names were later swapped by mistake, and the swap stuck.

What it is used for

Green phosphors in fluorescent lamps and screens; Terfenol-D, an alloy that changes shape in a magnetic field and drives sonar and precision actuators; and small additions to neodymium magnets that must work in hot motors.

In compounds

Tb₄O₇terbium oxideTbCl₃terbium chloride