All practice pages/Interatomic theory/Diatomics

8O₂32.00 g/mol

The molecule

O₂

Two oxygen atoms joined by a double bond: the gas that fire, rust and every breath depend on.

The atom it is made ofOxygenRead about the element

The bond

OO
Bond
double, 2 shared pairs
Bond length
121 pm
Bond energy
498 kJ/mol
Molar mass
32.00 g/mol
Also called
oxygen gas, dioxygen

Properties

At 25 °C
colorless, odorless gas; the liquid is pale blue
Melting point
−218.8 °C
Boiling point
−183.0 °C
Density
1.43 g/L at 0 °C and 1 atm, a little denser than air
In water
about 8 mg per liter at 25 °C, which is all the oxygen a fish gets
Odd fact
it is attracted to a magnet; liquid oxygen poured between the poles of a strong magnet hangs there

How it behaves

Oxygen does not burn, but almost everything burns in it. It reacts with nearly every element to form oxides: quickly and hot in a fire, slowly in the rusting of iron, and in a controlled way inside every cell of your body, where glucose is oxidized to carbon dioxide and water to release energy. Things that only smolder in air burn brightly in pure oxygen; a glowing splint bursts back into flame, which is the classic test for the gas.

How it is made

Industry distills it from liquid air alongside nitrogen. Home oxygen concentrators pull it from air with adsorbent beds that trap the nitrogen. Splitting water with electricity gives it too. In a lab, hydrogen peroxide dripped onto manganese dioxide fizzes with oxygen. Nature makes it by photosynthesis.

What it is used for

Steelmaking uses the most: oxygen blown through molten iron burns out the carbon. Medical oxygen, oxy-acetylene cutting and welding torches, rocket engines that burn liquid oxygen with hydrogen or kerosene, water-treatment plants and fish farms all depend on it.

Handle with care

It makes fires burn far hotter and faster. Grease or oil in contact with high-pressure oxygen can ignite on its own, so oxygen fittings are kept oil-free. Liquid oxygen causes severe cold burns.