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39Y88.91

Element 39, a transition metal

Yttrium

The first element pulled out of the ores of Ytterby, a Swedish village that gave its name to four elements.

At a glance

Symbol
Y
Atomic number
39
Average atomic mass
88.91
Group
3
Period
5
Family
transition metal
Electron configuration
[Kr] 4d¹ 5s²
Electronegativity
1.22
Common ions
Y³⁺

On the table

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Period 5, group 3. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Yttrium has 39 electrons, one for every proton, so the atom carries no charge. Below are the same 39 electrons written two ways.

Simple form: electrons per shell

Y
shell 12shell 28shell 318shell 49shell 52
Counting outward from the nucleus: 2, 8, 18, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹ 5s²

Short form: [Kr] 4d¹ 5s², where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s² 4d¹, because a subshell fills by its energy, not by its shell number.

4d¹↑
5s²↑↓
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Yttrium sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones yttrium can lose, gain or share, so they are the ones that decide what it bonds with.

Yttrium gives up three electrons to form Y³⁺, and it behaves so much like the lanthanides that it is counted among the rare earth elements.

Properties

State at 25 °C
solid
What it looks like
silvery-white metal
Melting point
1522 °C
Boiling point
3345 °C
Density
4.47 g/cm³

Where it is found

Found with the lanthanides in rare earth ores such as xenotime, monazite and ion-adsorption clays, mostly in China. Rocks brought back from the Moon are unusually rich in it.

Discovery and name

Johan Gadolin identified a new earth, yttria, in 1794 in a black mineral from the Ytterby quarry near Stockholm, and Friedrich Wöhler isolated the metal in 1828. The same village also named ytterbium, terbium and erbium.

What it is used for

Yttrium aluminum garnet (YAG) crystals make the phosphors in white LEDs and the lasers used in surgery and metal cutting. Yttria-stabilized zirconia makes tough ceramics, dental crowns and the oxygen sensors in car exhausts, and yttrium barium copper oxide was one of the first superconductors to work at liquid nitrogen temperature.

In compounds

Y₂O₃yttrium oxide, yttriaY₃Al₅O₁₂yttrium aluminum garnet, YAGYBa₂Cu₃O₇YBCO, a high-temperature superconductorYVO₄yttrium vanadate, laser crystals