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87Fr[223]

Element 87, an alkali metal

Francium

The last element discovered in nature, so short-lived that only about an ounce of it exists on Earth at any moment.

At a glance

Symbol
Fr
Atomic number
87
Mass number of its longest-lived isotope
[223]
Group
1
Period
7
Family
alkali metal
Electron configuration
[Rn] 7s¹
Valence electrons
1
Electronegativity
0.70
Common ions
Fr⁺
Isotopes
none are stable; ²²³Fr, the longest-lived, has a half-life of 22 minutes

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 7, group 1. The other alkali metals are tinted, and every cell opens its own article.

Electrons and bonding

Francium has 87 electrons, one for every proton, so the atom carries no charge. Below are the same 87 electrons written two ways.

Simple form: electrons per shell

Fr
shell 12shell 28shell 318shell 432shell 518shell 68shell 71
Counting outward from the nucleus: 2, 8, 18, 32, 18, 8, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶ 7s¹

Short form: [Rn] 7s¹, where [Rn] stands for the 86 electrons radon already has.

7s¹↑
The boxes hold the electrons beyond [Rn]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Francium sits in period 7 and has 7 shells. The period number counts the shells.

What that means for bonding

Fr

The outer shell holds 1 electron. Those are the ones francium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 1 means 1.

One valence electron, which francium gives up easily to form the Fr⁺ ion. Like the other alkali metals, it reacts with water.

Properties

State at 25 °C
solid
What it looks like
never collected in visible amounts; expected to be a soft metal
Melting point
27 °C (estimated)
Boiling point
not known
Density
not measured

Where it is found

Formed in tiny amounts in uranium and thorium ores as actinium decays. Only about 20 to 30 grams are thought to exist in Earth's crust at any moment.

Discovery and name

Marguerite Perey, a former assistant of Marie Curie, found it in 1939 at the Curie Institute in Paris while purifying actinium, and named it after France. In 1962 she became the first woman elected to the French Academy of Sciences, as a corresponding member.

What it is used for

None outside research. Physicists trap clouds of a few hundred thousand francium atoms with lasers to test theories of atomic structure.

Handle with care

Intensely radioactive; it is only ever handled a few atoms at a time.