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20Ca40.08

Element 20, an alkaline earth metal

Calcium

The metal in chalk, marble, bones and cement, and the most abundant metal in your body.

At a glance

Symbol
Ca
Atomic number
20
Average atomic mass
40.08
Group
2
Period
4
Family
alkaline earth metal
Electron configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 4s², or [Ar] 4s²
Valence electrons
2
Electronegativity
1.00
Common ions
Ca²⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 2. The other alkaline earth metals are tinted, and every cell opens its own article.

Electrons and bonding

Calcium has 20 electrons, one for every proton, so the atom carries no charge. Below are the same 20 electrons written two ways.

Simple form: electrons per shell

Ca
shell 12shell 28shell 38shell 42
Counting outward from the nucleus: 2, 8, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 4s²

Short form: [Ar] 4s², where [Ar] stands for the 18 electrons argon already has.

4s²↑↓
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p⁶, and 2 + 6 is 8.

Calcium sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

Ca

The outer shell holds 2 electrons. Those are the ones calcium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 2 means 2.

Two valence electrons, which calcium gives up to form the Ca²⁺ ion in its compounds.

Properties

State at 25 °C
solid
What it looks like
dull silvery-white metal, harder than sodium
Melting point
842 °C
Boiling point
1484 °C
Density
1.54 g/cm³
Flame test
orange-red

Where it is found

About 4% of the crust by mass, in limestone, chalk and marble (all calcium carbonate), gypsum and fluorite. Seashells and coral are calcium carbonate too, and about 1 kg of an adult's body is calcium, almost all of it in bones and teeth.

Discovery and name

Humphry Davy isolated it in 1808 by electrolysis of a mixture of lime and mercury oxide. Lime itself had been made by heating limestone since ancient times. The name comes from the Latin calx, lime.

What it is used for

Cement and concrete depend on lime made from limestone, and plaster and drywall are gypsum. Calcium also refines steel, calcium chloride melts ice and settles dust on roads, and calcium carbonate is chalk, an antacid and a filler in paper, paint and toothpaste.

In compounds

CaCO₃calcium carbonate: limestone, marble, chalkCaOcalcium oxide, quicklimeCa(OH)₂calcium hydroxide, slaked limeCaSO₄·2H₂OgypsumCaCl₂calcium chloride, road saltCa₅(PO₄)₃OHhydroxyapatite, in bone and enamel