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6C12.01

Element 6, a nonmetal

Carbon

The element of life and of fuel. Its atoms link into chains and rings, building millions of compounds.

At a glance

Symbol
C
Atomic number
6
Average atomic mass
12.01
Group
14
Period
2
Family
nonmetal
Electron configuration
1s² 2s² 2p², or [He] 2s² 2p²
Valence electrons
4
Electronegativity
2.55
Common ions
shares electrons in covalent bonds; C⁴⁻ in a few carbides
Isotopes
¹²C (98.9%) and ¹³C (1.1%); radioactive ¹⁴C, made in the upper atmosphere, is used for radiocarbon dating

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 2, group 14. The other nonmetals are tinted, and every cell opens its own article.

Electrons and bonding

Carbon has 6 electrons, one for every proton, so the atom carries no charge. Below are the same 6 electrons written two ways.

Simple form: electrons per shell

C
shell 12shell 24
Counting outward from the nucleus: 2, 4. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p²

Short form: [He] 2s² 2p², where [He] stands for the 2 electrons helium already has.

2s²↑↓
2p²↑↑
The boxes hold the electrons beyond [He]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p², and 2 + 2 is 4.

Carbon sits in period 2 and has 2 shells. The period number counts the shells.

What that means for bonding

C

The outer shell holds 4 electrons. Those are the ones carbon can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 14 means 4.

Four valence electrons, halfway to a full shell, so carbon shares electrons instead of gaining or losing them. It forms four covalent bonds, including to other carbon atoms in chains, rings, and double and triple bonds.

Properties

State at 25 °C
solid
What it looks like
soft, black graphite or clear, very hard diamond, depending on how the atoms are arranged
Sublimes
at about 3642 °C, going straight from solid to gas
Density
2.27 g/cm³ for graphite, 3.51 g/cm³ for diamond

Where it is found

About 0.02% of the crust by mass, mostly locked in limestone, chalk and marble as carbonates. It is in coal, oil and natural gas, in the air as carbon dioxide, and in every living thing: about 18% of your body by mass. Diamond and graphite also occur naturally.

Discovery and name

Known since prehistory as charcoal and soot. Antoine Lavoisier listed it as an element in 1789, and in 1797 Smithson Tennant showed that burning diamond gives nothing but carbon dioxide. The name comes from the Latin carbo, charcoal. A third form, the soccer-ball-shaped C₆₀ molecule, was discovered in 1985.

What it is used for

Coal, oil and natural gas supply most of the world's energy. Coke made from coal turns iron ore into iron, and a little carbon turns iron into steel. Graphite makes pencil leads, lubricants and battery electrodes; diamond cuts and drills; activated charcoal filters water and air; and carbon fiber makes stiff, light bike frames and aircraft parts.

In compounds

CO₂carbon dioxideCH₄methane, natural gasCaCO₃calcium carbonate, limestoneC₆H₁₂O₆glucoseCOcarbon monoxide, a poisonSiCsilicon carbide, an abrasive