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35Br79.90

Element 35, a halogen

Bromine

The only nonmetal that is a liquid at room temperature: dark red, heavy, fuming, and named for its smell.

In nature it is never aloneBr₂Read about the molecule

At a glance

Symbol
Br
Atomic number
35
Average atomic mass
79.90
Group
17
Period
4
Family
halogen
Electron configuration
[Ar] 3d¹⁰ 4s² 4p⁵
Valence electrons
7
Electronegativity
2.96
Common ions
Br⁻ (bromide), as in NaBr and AgBr
Isotopes
⁷⁹Br (50.7%) and ⁸¹Br (49.3%), an almost even split

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 17: the third rung down the stem of the 7. The other halogens are tinted, and every cell opens its own article.

Electrons and bonding

Bromine has 35 electrons, one for every proton, so the atom carries no charge. Below are the same 35 electrons written two ways.

Simple form: electrons per shell

Br
shell 12shell 28shell 318shell 47
Counting outward from the nucleus: 2, 8, 18, 7. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁵

Short form: [Ar] 3d¹⁰ 4s² 4p⁵, where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s² 3d¹⁰ 4p⁵, because a subshell fills by its energy, not by its shell number.

3d¹⁰↑↓↑↓↑↓↑↓↑↓
4s²↑↓
4p⁵↑↓↑↓↑
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Bromine sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

Br

The outer shell holds 7 electrons. Those are the ones bromine can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 17 means 7.

Seven valence electrons, one short of a full shell, so it gains one to form the Br⁻ ion or shares one in a covalent bond.

Seven valence electrons, one short of eight. Two bromine atoms share one pair, a single bond.

Properties

State at 25 °C
liquid
What it looks like
dark red-brown liquid made of Br₂ molecules, giving off red-brown vapor
Melting point
−7.2 °C
Boiling point
58.8 °C
Density
3.11 g/cm³

Where it is found

Rare in rock, about 0.0004% of the crust, but seawater holds about 65 mg of bromide per liter and some brines hold far more. The Dead Sea and the deep brines under Arkansas and Michigan are the main sources.

Discovery and name

Antoine Jérôme Balard, a 23-year-old pharmacy student in Montpellier, isolated it from salt-marsh brine in 1826. Carl Löwig had found it a year earlier in Germany but published later. The name is from the Greek bromos, stench.

What it is used for

Bromine compounds make flame retardants for plastics and electronics, dense drilling fluids for oil wells, pool and spa sanitizers, and some medicines and dyes. Silver bromide was the light-sensitive layer of photographic film.

In compounds

NaBrsodium bromideAgBrsilver bromide, photographic filmKBrpotassium bromide, an early sedativeCaBr₂calcium bromide, a heavy drilling fluidCH₃Brmethyl bromide, a fumigantHBrhydrobromic acid