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19K39.10

Element 19, an alkali metal

Potassium

A soft metal that bursts into lilac flame on water, and an ion every nerve and muscle cell in your body depends on.

At a glance

Symbol
K
Atomic number
19
Average atomic mass
39.10
Group
1
Period
4
Family
alkali metal
Electron configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹, or [Ar] 4s¹
Valence electrons
1
Electronegativity
0.82
Common ions
K⁺
Isotopes
³⁹K (93.3%) and ⁴¹K (6.7%), plus a trace of radioactive ⁴⁰K, which makes bananas, and people, very slightly radioactive

On the table

Periodic table with Potassium highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 1. The other alkali metals are tinted, and every cell opens its own article.

Electrons and bonding

K

One valence electron, which potassium gives up easily to form the K⁺ ion. Like the other alkali metals, it reacts with water.

Properties

State at 25 °C
solid
What it looks like
soft, silvery metal that tarnishes almost instantly in air
Melting point
63.4 °C
Boiling point
759 °C
Density
0.89 g/cm³
Flame test
lilac

Where it is found

About 2% of the crust by mass, in feldspar and mica. It is mined as potash from beds of salts such as sylvite (KCl) left by ancient seas; the largest deposits are in Saskatchewan, Canada. Bananas, potatoes and beans are rich in it.

Discovery and name

Humphry Davy isolated it in 1807 by passing electricity through molten potassium hydroxide, the first metal ever isolated that way; the tiny globules burst into flame. The name comes from potash, the ash of plants soaked in pots. The symbol K comes from kalium, from the Arabic al-qali, plant ashes.

What it is used for

About 95% of potash goes into fertilizer. Potassium compounds also make soap (potassium hydroxide), glass, gunpowder and fireworks (potassium nitrate), salt substitutes (potassium chloride) and potassium iodide tablets for radiation emergencies.

In compounds

KClpotassium chloride, potashKNO₃potassium nitrate, saltpeterKOHpotassium hydroxideKMnO₄potassium permanganateK₂CO₃potassium carbonateKIpotassium iodide

Handle with care

Reacts with water even more violently than sodium, igniting the hydrogen it releases, so it is stored under oil. Old potassium can grow a crust of superoxide that explodes when cut.