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86Rn[222]

Element 86, a noble gas

Radon

A radioactive noble gas that seeps out of the ground into basements, and a leading cause of lung cancer.

At a glance

Symbol
Rn
Atomic number
86
Mass number of its longest-lived isotope
[222]
Group
18
Period
6
Family
noble gas
Electron configuration
[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p⁶
Valence electrons
8
Electronegativity
not measured
Isotopes
none are stable; ²²²Rn, with a half-life of 3.8 days, is the one found in homes

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, group 18. The other noble gases are tinted, and every cell opens its own article.

Electrons and bonding

Radon has 86 electrons, one for every proton, so the atom carries no charge. Below are the same 86 electrons written two ways.

Simple form: electrons per shell

Rn
shell 12shell 28shell 318shell 432shell 518shell 68
Counting outward from the nucleus: 2, 8, 18, 32, 18, 8. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶

Short form: [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p⁶, where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹⁴ 5d¹⁰ 6p⁶, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d¹⁰↑↓↑↓↑↓↑↓↑↓
6s²↑↓
6p⁶↑↓↑↓↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Radon sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

Rn

The outer shell holds 8 electrons. Those are the ones radon can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 18 means 8.

A full valence shell, like the other noble gases, but its outer electrons are held loosely enough that it can form a fluoride. Its radioactivity makes that chemistry hard to study.

Properties

State at 25 °C
gas
What it looks like
colorless, odorless, radioactive gas
Melting point
−71 °C
Boiling point
−61.7 °C
Density
9.73 g/L at 0 °C and 1 atm

Where it is found

Made continuously in soil and rock as uranium and radium decay. It seeps into buildings, especially basements, and is the largest source of natural radiation for most people.

Discovery and name

Ernest Rutherford and Robert Owens noticed a radioactive gas given off by thorium in 1899, and Friedrich Ernst Dorn found the one given off by radium in 1900. William Ramsay and Robert Whytlaw-Gray isolated it in 1908 and called it niton, from the Latin for shining. The name radon, after radium, was adopted in 1923.

What it is used for

Once used in cancer radiotherapy; today it is measured far more than it is used. Radon levels help scientists trace the movement of air and groundwater and study earthquakes.

In compounds

RnF₂radon difluoride

Handle with care

Breathing radon for years raises the risk of lung cancer, especially for smokers; in the United States it is the second leading cause of lung cancer after smoking. Home test kits are cheap, and ventilating basements lowers the level.