All practice pages/Interatomic theory/Elements

93Np[237]

Element 93, an actinide

Neptunium

The first element heavier than uranium, named for the next planet out.

At a glance

Symbol
Np
Atomic number
93
Mass number of its longest-lived isotope
[237]
Group
none; it sits in the actinide row below the table
Period
7
Family
actinide
Electron configuration
[Rn] 5f⁴ 6d¹ 7s²
Electronegativity
1.36
Common ions
+5 in water, as NpO₂⁺; anywhere from +3 to +7
Isotopes
none are stable; ²³⁷Np, with a half-life of 2.1 million years, is the longest-lived

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 7, in the actinide row set below the main table. The other actinides are tinted, and every cell opens its own article.

Electrons and bonding

Neptunium has 93 electrons, one for every proton, so the atom carries no charge. Below are the same 93 electrons written two ways.

Simple form: electrons per shell

Np
shell 12shell 28shell 318shell 432shell 522shell 69shell 72
Counting outward from the nucleus: 2, 8, 18, 32, 22, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 5f⁴ 6s² 6p⁶ 6d¹ 7s²

Short form: [Rn] 5f⁴ 6d¹ 7s², where [Rn] stands for the 86 electrons radon already has.

That list runs by shell. In the order the subshells fill it reads [Rn] 7s² 5f⁴ 6d¹, because a subshell fills by its energy, not by its shell number.

5f⁴↑↑↑↑
6d¹↑
7s²↑↓
The boxes hold the electrons beyond [Rn]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Neptunium sits in period 7 and has 7 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones neptunium can lose, gain or share, so they are the ones that decide what it bonds with.

Radioactive, like every actinide. It gives up electrons to form positive ions.

Properties

State at 25 °C
solid
What it looks like
silvery, radioactive metal
Melting point
644 °C
Boiling point
3902 °C
Density
20.3 g/cm³

Where it is found

Tiny traces form in uranium ores. Nearly all of it comes from spent nuclear fuel.

Discovery and name

Edwin McMillan and Philip Abelson made it in 1940 at Berkeley by bombarding uranium with neutrons, the first element beyond uranium. Uranium had been named for Uranus, so they named this one for Neptune.

What it is used for

Neptunium-237 is irradiated to make plutonium-238 for spacecraft power sources, and it goes into some neutron detectors.

In compounds

NpO₂neptunium dioxideNpF₆neptunium hexafluoride

Handle with care

Radioactive, and it builds up in bone and the liver.