All practice pages/Interatomic theory/Elements

13Al26.98

Element 13, a post-transition metal

Aluminum

The most abundant metal in the Earth's crust, once so hard to extract that it was a precious metal, and now cheap enough to wrap sandwiches in.

At a glance

Symbol
Al
Atomic number
13
Average atomic mass
26.98
Group
13
Period
3
Family
post-transition metal
Electron configuration
1s² 2s² 2p⁶ 3s² 3p¹, or [Ne] 3s² 3p¹
Valence electrons
3
Electronegativity
1.61
Common ions
Al³⁺

On the table

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Period 3, group 13. The other post-transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Aluminum has 13 electrons, one for every proton, so the atom carries no charge. Below are the same 13 electrons written two ways.

Simple form: electrons per shell

Al
shell 12shell 28shell 33
Counting outward from the nucleus: 2, 8, 3. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p¹

Short form: [Ne] 3s² 3p¹, where [Ne] stands for the 10 electrons neon already has.

3s²↑↓
3p¹↑
The boxes hold the electrons beyond [Ne]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p⁶, and 2 + 6 is 8.

Aluminum sits in period 3 and has 3 shells. The period number counts the shells.

What that means for bonding

Al

The outer shell holds 3 electrons. Those are the ones aluminum can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 13 means 3.

Three valence electrons, which aluminum gives up to form the Al³⁺ ion. A thin film of aluminum oxide forms on the metal the moment it meets air and protects it from further corrosion.

Properties

State at 25 °C
solid
What it looks like
light, silvery-white metal
Melting point
660.3 °C
Boiling point
2519 °C
Density
2.70 g/cm³

Where it is found

About 8% of the crust by mass, the most abundant metal there, but always bound to oxygen in clays, feldspars and other minerals. It is mined as bauxite, a soft reddish ore rich in aluminum oxide, mainly in Australia, Guinea and China.

Discovery and name

Hans Christian Ørsted produced a small, impure amount in 1825 and Friedrich Wöhler a purer sample in 1827. For decades the metal was a luxury; a small aluminum pyramid was set atop the Washington Monument in 1884 as a showpiece. In 1886 Charles Martin Hall in the United States and Paul Héroult in France independently found how to extract it cheaply with electricity. The name comes from alum, a salt used since ancient times.

What it is used for

Drink cans, foil and food packaging; aircraft, car and train bodies; window frames; and overhead power lines, where it carries electricity at a fraction of copper's weight. Aluminum can be recycled again and again using about 5% of the energy needed to make it new.

In compounds

Al₂O₃aluminum oxide: corundum, ruby and sapphireAlCl₃aluminum chlorideAl₂(SO₄)₃aluminum sulfate, for water treatmentKAl(SO₄)₂·12H₂OalumAl(OH)₃aluminum hydroxide, an antacid