All practice pages/Interatomic theory/Elements

46Pd106.42

Element 46, a transition metal

Palladium

A precious metal that soaks up hundreds of times its own volume of hydrogen, and the catalyst inside most gasoline car exhausts.

At a glance

Symbol
Pd
Atomic number
46
Average atomic mass
106.42
Group
10
Period
5
Family
transition metal
Electron configuration
[Kr] 4d¹⁰
Electronegativity
2.20
Common ions
Pd²⁺ in most compounds

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 10. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Palladium has 46 electrons, one for every proton, so the atom carries no charge. Below are the same 46 electrons written two ways.

Simple form: electrons per shell

Pd
shell 12shell 28shell 318shell 418
Counting outward from the nucleus: 2, 8, 18, 18. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰

Short form: [Kr] 4d¹⁰, where [Kr] stands for the 36 electrons krypton already has.

4d¹⁰↑↓↑↓↑↓↑↓↑↓
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Palladium sits in period 5, but its outermost shell is empty in the ground state, so the count stops at 4.

What that means for bonding

The outer shell holds 18 electrons. Those are the ones palladium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, palladium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-white metal
Melting point
1554.9 °C
Boiling point
2963 °C
Density
12.0 g/cm³

Where it is found

Mined with platinum and nickel, mostly at Norilsk in Russia and in South Africa.

Discovery and name

William Hyde Wollaston isolated it from platinum ore in 1802 and, before announcing it, offered it anonymously for sale in a London shop in 1803 as new silver, which led other chemists to suspect a fraud. He named it after the asteroid Pallas, discovered in 1802.

What it is used for

Most goes into catalytic converters, especially for gasoline cars. It also goes into electronics, dental alloys, white gold jewelry and membranes that purify hydrogen. Palladium catalysts join carbon atoms together when making medicines, work recognized by the 2010 Nobel Prize in Chemistry.

In compounds

PdCl₂palladium(II) chloridePd(CH₃COO)₂palladium acetate, a catalystPdHₓpalladium hydride