All practice pages/Interatomic theory/Elements

44Ru101.07

Element 44, a transition metal

Ruthenium

A hard platinum-group metal named for Russia, found in hard drives, electrical contacts and Nobel Prize-winning catalysts.

At a glance

Symbol
Ru
Atomic number
44
Average atomic mass
101.07
Group
8
Period
5
Family
transition metal
Electron configuration
[Kr] 4d⁷ 5s¹
Electronegativity
2.20
Common ions
+3 and +4 are most common; +8 in the volatile oxide RuO₄

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 8. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Ruthenium has 44 electrons, one for every proton, so the atom carries no charge. Below are the same 44 electrons written two ways.

Simple form: electrons per shell

Ru
shell 12shell 28shell 318shell 415shell 51
Counting outward from the nucleus: 2, 8, 18, 15, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁷ 5s¹

Short form: [Kr] 4d⁷ 5s¹, where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s¹ 4d⁷, because a subshell fills by its energy, not by its shell number.

4d⁷↑↓↑↓↑↑↑
5s¹↑
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Ruthenium sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones ruthenium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, ruthenium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, brittle, silvery-white metal
Melting point
2334 °C
Boiling point
4150 °C
Density
12.1 g/cm³

Where it is found

One of the rarest metals, found with platinum in ores from South Africa and Russia and recovered while refining platinum and nickel.

Discovery and name

Karl Ernst Claus isolated it in 1844 at Kazan University from the residue left after dissolving platinum ore from the Ural Mountains, and named it after Ruthenia, a Latin name for Russia.

What it is used for

Thin ruthenium layers in hard disk drives, electrical contacts and chip resistors; a hardener in platinum and palladium jewelry; catalysts, including the Grubbs catalysts recognized by the 2005 Nobel Prize in Chemistry; and light-absorbing dyes for some solar cells.

In compounds

RuO₂ruthenium dioxide, in chip resistorsRuO₄ruthenium tetroxide, a strong oxidizerRuCl₃ruthenium(III) chloride

Handle with care

Ruthenium tetroxide is volatile, toxic and can explode.