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58Ce140.12

Element 58, a lanthanide

Cerium

The most abundant rare earth, the spark in a lighter flint, and the powder that polishes glass.

At a glance

Symbol
Ce
Atomic number
58
Average atomic mass
140.12
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f¹ 5d¹ 6s²
Electronegativity
1.12
Common ions
Ce³⁺ and Ce⁴⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Cerium has 58 electrons, one for every proton, so the atom carries no charge. Below are the same 58 electrons written two ways.

Simple form: electrons per shell

Ce
shell 12shell 28shell 318shell 419shell 59shell 62
Counting outward from the nucleus: 2, 8, 18, 19, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹ 5s² 5p⁶ 5d¹ 6s²

Short form: [Xe] 4f¹ 5d¹ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹ 5d¹, because a subshell fills by its energy, not by its shell number.

4f¹↑
5d¹↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹, and 2 + 6 + 10 + 1 is 19.

Cerium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones cerium can lose, gain or share, so they are the ones that decide what it bonds with.

Unusually for a lanthanide, cerium readily forms Ce⁴⁺ as well as Ce³⁺, because losing a fourth electron leaves it with the same stable electron arrangement as xenon.

Properties

State at 25 °C
solid
What it looks like
soft, iron-gray metal
Melting point
798 °C
Boiling point
3424 °C
Density
6.77 g/cm³

Where it is found

More abundant in the crust than copper. It is the main rare earth in bastnäsite and monazite, mined mostly in China and at Mountain Pass, California.

Discovery and name

Jöns Jacob Berzelius and Wilhelm Hisinger in Sweden, and independently Martin Heinrich Klaproth in Germany, found it in 1803. It was named after the asteroid Ceres, discovered two years earlier.

What it is used for

Cerium oxide is the standard powder for polishing glass, from lenses to phone screens. Cerium also goes into catalytic converters and self-cleaning oven walls, and ferrocerium, an alloy that throws hot sparks when scratched, makes lighter flints and fire starters.

In compounds

CeO₂cerium(IV) oxide, glass polishCe(SO₄)₂cerium(IV) sulfate, a lab oxidizerCeCl₃cerium(III) chloride(NH₄)₂Ce(NO₃)₆ceric ammonium nitrate