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79Au196.97

Element 79, a transition metal

Gold

Beautiful, rare and almost indestructible, gold has been treasured for as long as people have made things.

At a glance

Symbol
Au
Atomic number
79
Average atomic mass
196.97
Group
11
Period
6
Family
transition metal
Electron configuration
[Xe] 4f¹⁴ 5d¹⁰ 6s¹
Electronegativity
2.54
Common ions
Au⁺ and Au³⁺

On the table

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Period 6, group 11. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Gold has 79 electrons, one for every proton, so the atom carries no charge. Below are the same 79 electrons written two ways.

Simple form: electrons per shell

Au
shell 12shell 28shell 318shell 432shell 518shell 61
Counting outward from the nucleus: 2, 8, 18, 32, 18, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s¹

Short form: [Xe] 4f¹⁴ 5d¹⁰ 6s¹, where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s¹ 4f¹⁴ 5d¹⁰, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d¹⁰↑↓↑↓↑↓↑↓↑↓
6s¹↑
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Gold sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones gold can lose, gain or share, so they are the ones that decide what it bonds with.

Gold holds its electrons unusually tightly for a metal, so it resists oxygen, water and nearly all acids. Aqua regia, a mixture of nitric and hydrochloric acids, is one of the few things that dissolves it.

Properties

State at 25 °C
solid
What it looks like
soft, bright yellow metal that never tarnishes
Melting point
1064.2 °C
Boiling point
2856 °C
Density
19.3 g/cm³
Odd fact
so malleable that one gram can be beaten into a sheet about a square meter across

Where it is found

Found mostly as the metal itself, in quartz veins and as grains and nuggets in river gravels, and also in copper ores. China, Australia and Russia mine the most. All the gold ever mined would fit in a cube about 22 meters on a side.

Discovery and name

Known since prehistory; gold objects from the Varna burial ground in Bulgaria are more than 6,000 years old. The name is Old English, and the symbol Au comes from its Latin name aurum.

What it is used for

Jewelry takes about half, and investment bars and coins much of the rest. Gold also plates electrical connectors that must never corrode, repairs teeth, and coats astronaut helmet visors and satellite parts to reflect heat. Gold nanoparticles make the colored line on many rapid tests.

In compounds

AuCl₃gold(III) chlorideHAuCl₄chloroauric acidAuTe₂calaveriteK[Au(CN)₂]potassium dicyanoaurate, for plating