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56Ba137.33

Element 56, an alkaline earth metal

Barium

Heavy by name and poisonous as a soluble salt, yet swallowed safely as a white paste so doctors can X-ray the gut.

At a glance

Symbol
Ba
Atomic number
56
Average atomic mass
137.33
Group
2
Period
6
Family
alkaline earth metal
Electron configuration
[Xe] 6s²
Valence electrons
2
Electronegativity
0.89
Common ions
Ba²⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, group 2. The other alkaline earth metals are tinted, and every cell opens its own article.

Electrons and bonding

Barium has 56 electrons, one for every proton, so the atom carries no charge. Below are the same 56 electrons written two ways.

Simple form: electrons per shell

Ba
shell 12shell 28shell 318shell 418shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 18, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 6s²

Short form: [Xe] 6s², where [Xe] stands for the 54 electrons xenon already has.

6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Barium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

Ba

The outer shell holds 2 electrons. Those are the ones barium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 2 means 2.

Two valence electrons, which barium gives up to form the Ba²⁺ ion in its compounds.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-white metal that tarnishes quickly
Melting point
727 °C
Boiling point
1897 °C
Density
3.62 g/cm³
Flame test
apple green

Where it is found

Mined mostly as barite (BaSO₄), in China, India and Morocco, and as witherite (BaCO₃).

Discovery and name

Carl Wilhelm Scheele identified baryta, barium oxide, as a new earth in 1774, and Humphry Davy isolated the metal in 1808 by electrolysis. The name comes from the Greek barys, heavy, after the dense mineral barite.

What it is used for

Most barite is ground up for drilling mud, where its weight keeps oil and gas wells under control. Barium sulfate, which does not dissolve, is swallowed or given as an enema so the digestive tract shows up on X-rays. Barium compounds also make green fireworks, and barium goes into glass, ceramics and spark plugs.

In compounds

BaSO₄barium sulfate, barite and X-ray contrastBaCO₃barium carbonate, witheriteBa(NO₃)₂barium nitrate, green fireworksBaTiO₃barium titanate, in capacitorsBaCl₂barium chloride

Handle with care

Barium compounds that dissolve in water, such as barium chloride and barium carbonate, are poisonous. Barium sulfate is safe for X-rays only because it does not dissolve.