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35Br₂159.80 g/mol

The molecule

Br₂

Two bromine atoms sharing a single bond: a dark red liquid that fumes at room temperature, one of only two elements that do.

The atom it is made ofBromineRead about the element

The bond

BrBr
Bond
single, 1 shared pair
Bond length
228 pm
Bond energy
193 kJ/mol
Molar mass
159.80 g/mol
Also called
bromine, dibromine; bromine liquid

Properties

At 25 °C
dark red-brown liquid that gives off red-brown vapor, with a sharp, irritating smell
Melting point
−7.2 °C
Boiling point
58.8 °C
Density
3.10 g/mL, more than three times that of water
In water
about 35 g per liter, an orange solution called bromine water; it dissolves much better in hexane
Odd fact
one of only two elements liquid at room temperature; mercury is the other

How it behaves

Reactive, though less so than chlorine. Aluminum foil dropped into it bursts into flame, and phosphorus ignites. It adds across carbon–carbon double bonds without any heat or catalyst, and the orange color vanishes as it does, which makes bromine water the standard test for an unsaturated compound. It displaces iodine from iodide salts and is itself displaced by chlorine.

How it is made

Chlorine gas is bubbled through acidified seawater or brine; it oxidizes the bromide to bromine, which is blown out of the solution with air or steam and condensed. The United States (Arkansas brines), Israel and Jordan (the Dead Sea) and China produce most of it.

What it is used for

Flame retardants for plastics and electronics take the largest share. Dense bromide brines are pumped into oil wells to control pressure while drilling. Silver bromide was the light-sensitive layer in photographic film for a century. Bromine compounds also serve as pool sanitizers, in pharmaceuticals and in dyes.

Handle with care

Corrosive. Liquid bromine burns skin slowly and deeply, and the vapor damages eyes and lungs at low concentrations. It is stored in glass with Teflon-lined caps and handled in a fume hood with thick gloves, with a bottle of sodium thiosulfate solution nearby to neutralize spills.