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30Zn65.38

Element 30, a transition metal

Zinc

The coating that keeps steel from rusting, the core of the modern US penny, and a mineral your immune system cannot work without.

At a glance

Symbol
Zn
Atomic number
30
Average atomic mass
65.38
Group
12
Period
4
Family
transition metal
Electron configuration
[Ar] 3d¹⁰ 4s²
Electronegativity
1.65
Common ions
Zn²⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 12. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Zinc has 30 electrons, one for every proton, so the atom carries no charge. Below are the same 30 electrons written two ways.

Simple form: electrons per shell

Zn
shell 12shell 28shell 318shell 42
Counting outward from the nucleus: 2, 8, 18, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s²

Short form: [Ar] 3d¹⁰ 4s², where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s² 3d¹⁰, because a subshell fills by its energy, not by its shell number.

3d¹⁰↑↓↑↓↑↓↑↓↑↓
4s²↑↓
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Zinc sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones zinc can lose, gain or share, so they are the ones that decide what it bonds with.

Zinc gives up its two 4s electrons to form Zn²⁺ and almost never loses a d electron. Unlike most transition metals it has only one common ion, and its compounds are usually white.

Properties

State at 25 °C
solid
What it looks like
bluish-white, fairly brittle metal
Melting point
419.5 °C
Boiling point
907 °C
Density
7.13 g/cm³

Where it is found

Mined mostly as sphalerite (ZnS), often together with lead, in China, Peru and Australia. After iron, it is the most abundant trace metal in the human body.

Discovery and name

Brass, an alloy of copper and zinc, was made in ancient times, and zinc metal was being smelted in India centuries before Europe knew it. Andreas Marggraf isolated it in 1746 and described the method carefully. The name comes from the German Zink, perhaps from Zinke, prong, after the jagged crystals of the metal.

What it is used for

About half is used to galvanize steel, coating it so the zinc corrodes instead of the iron. Zinc also makes brass, die-cast parts and alkaline battery anodes, and US pennies minted since 1982 are 97.5% zinc under a thin copper plating. Zinc oxide goes into sunscreen, diaper cream, rubber tires and paint.

In compounds

ZnOzinc oxide, in sunscreen and rubberZnSzinc sulfide, sphaleriteZnCl₂zinc chloride, soldering fluxZnSO₄zinc sulfate, a supplement