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69Tm168.93

Element 69, a lanthanide

Thulium

Named for the mythical far north, it is one of the rarest of all the rare earth elements.

At a glance

Symbol
Tm
Atomic number
69
Average atomic mass
168.93
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f¹³ 6s²
Electronegativity
1.25
Common ions
Tm³⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Thulium has 69 electrons, one for every proton, so the atom carries no charge. Below are the same 69 electrons written two ways.

Simple form: electrons per shell

Tm
shell 12shell 28shell 318shell 431shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 31, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹³ 5s² 5p⁶ 6s²

Short form: [Xe] 4f¹³ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹³, because a subshell fills by its energy, not by its shell number.

4f¹³↑↓↑↓↑↓↑↓↑↓↑↓↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹³, and 2 + 6 + 10 + 13 is 31.

Thulium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones thulium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Tm³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
soft, silvery-gray metal
Melting point
1545 °C
Boiling point
1950 °C
Density
9.32 g/cm³

Where it is found

Found in small amounts in monazite, xenotime and ion-adsorption clays.

Discovery and name

Per Teodor Cleve found it in 1879 in erbium oxide and named it after Thule, an ancient name for a far northern land, often taken to mean Scandinavia.

What it is used for

Thulium-170 powers portable X-ray devices, thulium lasers are used in surgery, and thulium is studied for superconductors and phosphors. Its rarity and cost keep its uses few.

In compounds

Tm₂O₃thulium oxideTmCl₃thulium chloride