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24Cr52.00

Element 24, a transition metal

Chromium

The metal that keeps stainless steel stainless, puts the shine on chrome, and makes rubies red and emeralds green.

At a glance

Symbol
Cr
Atomic number
24
Average atomic mass
52.00
Group
6
Period
4
Family
transition metal
Electron configuration
[Ar] 3d⁵ 4s¹
Electronegativity
1.66
Common ions
Cr³⁺ (green); in the +6 state, chromate (yellow) and dichromate (orange)

On the table

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Period 4, group 6. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Chromium has 24 electrons, one for every proton, so the atom carries no charge. Below are the same 24 electrons written two ways.

Simple form: electrons per shell

Cr
shell 12shell 28shell 313shell 41
Counting outward from the nucleus: 2, 8, 13, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s¹

Short form: [Ar] 3d⁵ 4s¹, where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s¹ 3d⁵, because a subshell fills by its energy, not by its shell number.

3d⁵↑↑↑↑↑
4s¹↑
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d⁵, and 2 + 6 + 5 is 13.

Chromium sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones chromium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, chromium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, bright silvery metal that takes a high polish
Melting point
1907 °C
Boiling point
2671 °C
Density
7.15 g/cm³

Where it is found

Mined almost entirely as chromite, FeCr₂O₄, mostly in South Africa, Kazakhstan, India and Turkey. A trace of chromium in aluminum oxide makes ruby red, and in beryl it makes emerald green.

Discovery and name

Louis-Nicolas Vauquelin found it in 1797 in crocoite, a bright orange lead mineral from Siberia, and isolated the metal the next year. He named it from the Greek chroma, color, because its compounds come in so many colors.

What it is used for

Most goes into stainless steel, which needs at least about 10.5% chromium to form the thin, self-healing oxide film that stops rust. Chrome plating protects and decorates car parts, faucets and tools. Chromium compounds also tan leather, color paints and glass, and preserve wood.

In compounds

Cr₂O₃chromium(III) oxide, chrome greenK₂Cr₂O₇potassium dichromate, orangePbCrO₄lead chromate, chrome yellowCrO₃chromium trioxide, for chrome platingFeCr₂O₄chromite ore

Handle with care

Chromium in the +6 state, as in chromates and dichromates, is toxic and causes cancer, so its use is tightly controlled. Chromium metal and chromium(III) compounds are far less harmful.