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27Co58.93

Element 27, a transition metal

Cobalt

Named after a mine goblin, it makes the deepest blue in glass and porcelain and keeps the batteries of phones and electric cars running.

At a glance

Symbol
Co
Atomic number
27
Average atomic mass
58.93
Group
9
Period
4
Family
transition metal
Electron configuration
[Ar] 3d⁷ 4s²
Electronegativity
1.88
Common ions
Co²⁺ (pink in water, blue when dry) and Co³⁺

On the table

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Period 4, group 9. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Cobalt has 27 electrons, one for every proton, so the atom carries no charge. Below are the same 27 electrons written two ways.

Simple form: electrons per shell

Co
shell 12shell 28shell 315shell 42
Counting outward from the nucleus: 2, 8, 15, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁷ 4s²

Short form: [Ar] 3d⁷ 4s², where [Ar] stands for the 18 electrons argon already has.

That list runs by shell. In the order the subshells fill it reads [Ar] 4s² 3d⁷, because a subshell fills by its energy, not by its shell number.

3d⁷↑↓↑↓↑↑↑
4s²↑↓
The boxes hold the electrons beyond [Ar]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d⁷, and 2 + 6 + 7 is 15.

Cobalt sits in period 4 and has 4 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones cobalt can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, cobalt loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, lustrous, bluish-gray metal
Melting point
1495 °C
Boiling point
2927 °C
Density
8.86 g/cm³
Magnetic
yes, like iron and nickel

Where it is found

Mined almost entirely as a byproduct of copper and nickel. The Democratic Republic of the Congo produces about three quarters of the world's supply. A single cobalt atom sits at the center of vitamin B₁₂.

Discovery and name

Georg Brandt showed around 1735 that the blue color of certain ores came from a new metal, the first metal discovered since ancient times. Miners had long blamed these ores, which gave off poisonous arsenic fumes when smelted, on the kobold, a mischievous goblin of German folklore, and the name stuck.

What it is used for

Lithium-ion battery cathodes now use the largest share. Cobalt also goes into superalloys for jet engine turbine blades, strong magnets, hard cutting tools, and catalysts that remove sulfur from fuels. Cobalt blue has colored glass and porcelain for centuries, and radioactive cobalt-60 treats cancer and sterilizes medical supplies.

In compounds

CoCl₂cobalt(II) chloride, a humidity indicatorCoAl₂O₄cobalt blue pigmentLiCoO₂lithium cobalt oxide, a battery cathodeC₆₃H₈₈CoN₁₄O₁₄Pvitamin B₁₂