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40Zr91.22

Element 40, a transition metal

Zirconium

The metal neutrons pass straight through, which is why it wraps the fuel in nuclear reactors, and the stuff of cubic zirconia gems.

At a glance

Symbol
Zr
Atomic number
40
Average atomic mass
91.22
Group
4
Period
5
Family
transition metal
Electron configuration
[Kr] 4d² 5s²
Electronegativity
1.33
Common ions
Zr⁴⁺

On the table

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Period 5, group 4. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Zirconium has 40 electrons, one for every proton, so the atom carries no charge. Below are the same 40 electrons written two ways.

Simple form: electrons per shell

Zr
shell 12shell 28shell 318shell 410shell 52
Counting outward from the nucleus: 2, 8, 18, 10, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d² 5s²

Short form: [Kr] 4d² 5s², where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s² 4d², because a subshell fills by its energy, not by its shell number.

4d²↑↑
5s²↑↓
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Zirconium sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones zirconium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, zirconium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, lustrous, gray-white metal
Melting point
1855 °C
Boiling point
4409 °C
Density
6.52 g/cm³

Where it is found

Mined as zircon (ZrSiO₄) from beach sands, above all in Australia and South Africa. Zircon crystals are among the oldest things on Earth: grains from Western Australia are about 4.4 billion years old.

Discovery and name

Martin Heinrich Klaproth identified zirconia in 1789 in a zircon gem from Sri Lanka, and Jöns Jacob Berzelius isolated the metal in 1824. The name comes from the mineral zircon, probably from the Persian zargun, gold-colored.

What it is used for

Most zircon goes into ceramics, tiles and foundry molds. The metal, alloyed as Zircaloy, sheathes the uranium fuel in nuclear reactors because it barely absorbs neutrons and resists corrosion. Zirconium dioxide makes cubic zirconia gems, ceramic knives and dental crowns.

In compounds

ZrO₂zirconium dioxide, cubic zirconiaZrSiO₄zirconZrCl₄zirconium tetrachlorideZrCzirconium carbide