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42Mo95.95

Element 42, a transition metal

Molybdenum

A metal that keeps its strength in the heat, named after lead by mistake, and needed by the bacteria that turn air into plant food.

At a glance

Symbol
Mo
Atomic number
42
Average atomic mass
95.95
Group
6
Period
5
Family
transition metal
Electron configuration
[Kr] 4d⁵ 5s¹
Electronegativity
2.16
Common ions
+6 in the molybdate ion MoO₄²⁻ and most common compounds; also +4

On the table

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Period 5, group 6. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Molybdenum has 42 electrons, one for every proton, so the atom carries no charge. Below are the same 42 electrons written two ways.

Simple form: electrons per shell

Mo
shell 12shell 28shell 318shell 413shell 51
Counting outward from the nucleus: 2, 8, 18, 13, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁵ 5s¹

Short form: [Kr] 4d⁵ 5s¹, where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s¹ 4d⁵, because a subshell fills by its energy, not by its shell number.

4d⁵↑↑↑↑↑
5s¹↑
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Molybdenum sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones molybdenum can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, molybdenum loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, silvery-gray metal
Melting point
2623 °C
Boiling point
4639 °C
Density
10.2 g/cm³

Where it is found

Mined mostly as molybdenite (MoS₂) in China, Chile, Peru and the United States, often as a byproduct of copper mining. The Climax mine in Colorado was once the world's largest source.

Discovery and name

Carl Wilhelm Scheele showed in 1778 that molybdenite was neither graphite nor a lead ore, as people had assumed, and Peter Jacob Hjelm isolated the metal in 1781. The name comes from the Greek molybdos, lead, because the soft black mineral had been mistaken for lead ore.

What it is used for

About 80% goes into steels and alloys that must stay strong and resist corrosion when hot, for tools, armor, pipelines and engine parts. Molybdenum disulfide is a slippery lubricant, molybdenum catalysts remove sulfur from fuels, and molybdenum-99 is the source of the technetium-99m used in medical scans. Nitrogen-fixing bacteria need molybdenum in their key enzyme.

In compounds

MoS₂molybdenite, a lubricantMoO₃molybdenum trioxide(NH₄)₂MoO₄ammonium molybdateNa₂MoO₄sodium molybdate, a fertilizer additive