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51Sb121.76

Element 51, a metalloid

Antimony

A brittle metalloid once ground into ancient eyeliner, now mostly used to keep plastics and fabrics from catching fire.

At a glance

Symbol
Sb
Atomic number
51
Average atomic mass
121.76
Group
15
Period
5
Family
metalloid
Electron configuration
[Kr] 4d¹⁰ 5s² 5p³
Valence electrons
5
Electronegativity
2.05
Common ions
+3 and +5 in most compounds; −3 in antimonides

On the table

Periodic table with Antimony highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 15. The other metalloids are tinted, and every cell opens its own article.

Electrons and bonding

Sb

Five valence electrons, like nitrogen and phosphorus. Antimony mostly shares electrons in covalent bonds, in the +3 or +5 state with oxygen, sulfur and chlorine.

Properties

State at 25 °C
solid
What it looks like
brittle, silvery, lustrous metalloid
Melting point
630.6 °C
Boiling point
1587 °C
Density
6.69 g/cm³

Where it is found

Mined mainly as stibnite (Sb₂S₃), with China, Tajikistan and Russia supplying most of it.

Discovery and name

Stibnite was ground into kohl, a black eye cosmetic, in ancient Egypt, and objects of antimony metal survive from the ancient world. Vannoccio Biringuccio described extracting the metal in 1540. The origin of the name is uncertain; the symbol Sb comes from its Latin name stibium.

What it is used for

Antimony trioxide makes flame retardants in plastics, textiles and electronics work better, and takes the largest share. Antimony hardens the lead in car batteries and bullets, and it goes into semiconductors, glass and the catalysts used to make PET plastic bottles.

In compounds

Sb₂O₃antimony trioxide, in flame retardantsSb₂S₃stibnite, ancient kohlSbCl₃antimony trichlorideInSbindium antimonide, infrared detectors

Handle with care

Antimony and many of its compounds are toxic, in ways similar to arsenic but milder.