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32Ge72.63

Element 32, a metalloid

Germanium

The metalloid Mendeleev called eka-silicon, and the material of the very first transistor.

At a glance

Symbol
Ge
Atomic number
32
Average atomic mass
72.63
Group
14
Period
4
Family
metalloid
Electron configuration
[Ar] 3d¹⁰ 4s² 4p²
Valence electrons
4
Electronegativity
2.01
Common ions
forms no simple ions; +4 in compounds such as GeO₂

On the table

Periodic table with Germanium highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 4, group 14. The other metalloids are tinted, and every cell opens its own article.

Electrons and bonding

Ge

Four valence electrons, like carbon and silicon. Germanium shares them in four covalent bonds, and in the pure crystal that arrangement makes it a semiconductor.

Properties

State at 25 °C
solid
What it looks like
hard, brittle, grayish-white metalloid with a metallic shine
Melting point
938.3 °C
Boiling point
2833 °C
Density
5.32 g/cm³

Where it is found

Rare and spread thin. It is recovered as a byproduct of zinc refining and from the ash of certain coals, mainly in China.

Discovery and name

Clemens Winkler found it in 1886 in argyrodite, a silver mineral from Saxony, and named it after his homeland, Germany. Its atomic mass, density and oxide matched Mendeleev's 1871 predictions for eka-silicon almost exactly.

What it is used for

Fiber-optic cables, whose glass cores contain germanium dioxide; lenses and windows for infrared cameras and night vision; and high-efficiency solar cells for satellites. The first transistor, built at Bell Labs in 1947, was made of germanium.

In compounds

GeO₂germanium dioxide, in optical fiberGeCl₄germanium tetrachlorideGeH₄germaneSiGesilicon-germanium, fast chips