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48Cd112.41

Element 48, a transition metal

Cadmium

A soft metal behind brilliant yellow and red paints and rechargeable batteries, and a toxic one behind a mass poisoning in Japan.

At a glance

Symbol
Cd
Atomic number
48
Average atomic mass
112.41
Group
12
Period
5
Family
transition metal
Electron configuration
[Kr] 4d¹⁰ 5s²
Electronegativity
1.69
Common ions
Cd²⁺

On the table

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Period 5, group 12. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Cadmium has 48 electrons, one for every proton, so the atom carries no charge. Below are the same 48 electrons written two ways.

Simple form: electrons per shell

Cd
shell 12shell 28shell 318shell 418shell 52
Counting outward from the nucleus: 2, 8, 18, 18, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s²

Short form: [Kr] 4d¹⁰ 5s², where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s² 4d¹⁰, because a subshell fills by its energy, not by its shell number.

4d¹⁰↑↓↑↓↑↓↑↓↑↓
5s²↑↓
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Cadmium sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones cadmium can lose, gain or share, so they are the ones that decide what it bonds with.

Cadmium gives up its two 5s electrons to form Cd²⁺, its only common ion, much like zinc above it.

Properties

State at 25 °C
solid
What it looks like
soft, bluish-white metal
Melting point
321.1 °C
Boiling point
767 °C
Density
8.69 g/cm³

Where it is found

No ores are mined for cadmium alone. It occurs in zinc ores, especially sphalerite, and is recovered during zinc refining.

Discovery and name

Friedrich Stromeyer found it in 1817 while investigating zinc carbonate that turned yellow when heated. The name comes from the Latin cadmia, an old name for zinc carbonate ore.

What it is used for

Nickel-cadmium rechargeable batteries used most of it, though they are being phased out. Cadmium telluride makes thin-film solar panels, cadmium pigments give artists' paints brilliant yellows, oranges and reds, and cadmium absorbs neutrons in some reactor control rods.

In compounds

CdScadmium sulfide, cadmium yellowCdTecadmium telluride, solar panelsCdSecadmium selenide, quantum dotsCd(OH)₂cadmium hydroxide, a battery electrode

Handle with care

Toxic, and a cause of cancer. Cadmium from mining waste in the Jinzū River basin of Japan caused itai-itai disease in the 20th century, which softened bones and caused severe pain.