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71Lu174.97

Element 71, a lanthanide

Lutetium

The last and densest of the lanthanides, named after Paris, and now a targeted cancer treatment.

At a glance

Symbol
Lu
Atomic number
71
Average atomic mass
174.97
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f¹⁴ 5d¹ 6s²
Electronegativity
1.27
Common ions
Lu³⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Lutetium has 71 electrons, one for every proton, so the atom carries no charge. Below are the same 71 electrons written two ways.

Simple form: electrons per shell

Lu
shell 12shell 28shell 318shell 432shell 59shell 62
Counting outward from the nucleus: 2, 8, 18, 32, 9, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹ 6s²

Short form: [Xe] 4f¹⁴ 5d¹ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹⁴ 5d¹, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d¹↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Lutetium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones lutetium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Lu³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
hard, dense, silvery-white metal
Melting point
1663 °C
Boiling point
3402 °C
Density
9.84 g/cm³

Where it is found

One of the rarest and most expensive rare earths, recovered from monazite and xenotime.

Discovery and name

Georges Urbain in Paris, Carl Auer von Welsbach in Austria and Charles James in the United States each separated it from ytterbia around 1907. Urbain published first and named it after Lutetia, the Roman name for Paris.

What it is used for

Lutetium-177 is attached to molecules that seek out certain prostate and neuroendocrine cancers and destroys them with radiation from inside. Lutetium crystals detect gamma rays in PET scanners, lutetium catalysts help refine oil, and the slow decay of lutetium-176 dates meteorites and ancient rocks.

In compounds

Lu₂O₃lutetium oxideLu₂SiO₅lutetium oxyorthosilicate, PET scanner crystalsLuCl₃lutetium chloride