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4Be9.01

Element 4, an alkaline earth metal

Beryllium

A light, stiff metal that X-rays pass straight through, and one of the more dangerous elements to breathe in as dust.

At a glance

Symbol
Be
Atomic number
4
Average atomic mass
9.01
Group
2
Period
2
Family
alkaline earth metal
Electron configuration
1s² 2s², or [He] 2s²
Valence electrons
2
Electronegativity
1.57
Common ions
Be²⁺

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 2, group 2. The other alkaline earth metals are tinted, and every cell opens its own article.

Electrons and bonding

Beryllium has 4 electrons, one for every proton, so the atom carries no charge. Below are the same 4 electrons written two ways.

Simple form: electrons per shell

Be
shell 12shell 22
Counting outward from the nucleus: 2, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s²

Short form: [He] 2s², where [He] stands for the 2 electrons helium already has.

2s²↑↓
The boxes hold the electrons beyond [He]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14.

Beryllium sits in period 2 and has 2 shells. The period number counts the shells.

What that means for bonding

Be

The outer shell holds 2 electrons. Those are the ones beryllium can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 2 means 2.

Two valence electrons, but beryllium is so small that its bonds are more covalent than those of the other alkaline earth metals. In its ionic compounds it is Be²⁺.

Properties

State at 25 °C
solid
What it looks like
hard, brittle, steel-gray metal
Melting point
1287 °C
Boiling point
2471 °C
Density
1.85 g/cm³

Where it is found

Rare in the crust. It comes mainly from bertrandite mined in Utah and from beryl, the mineral whose green and blue gem forms are emerald and aquamarine.

Discovery and name

Louis-Nicolas Vauquelin found its oxide in beryl and emerald in 1798, and Friedrich Wöhler and Antoine Bussy each isolated the metal in 1828. It was long called glucinium, from the Greek for sweet, because its salts taste sweet. The name beryllium, from beryl, became official in 1949.

What it is used for

Windows for X-ray tubes and detectors, because X-rays pass through it. Copper-beryllium alloys make springs, electrical contacts and non-sparking tools for oil rigs and mines. It is light and stiff enough for aerospace parts: the 18 mirror segments of the James Webb Space Telescope are gold-coated beryllium.

In compounds

BeOberyllium oxide, a ceramic that conducts heatBe₃Al₂Si₆O₁₈beryl: emerald and aquamarineBeCl₂beryllium chlorideBe(OH)₂beryllium hydroxide

Handle with care

Breathing beryllium dust or fumes can cause chronic beryllium disease, a lasting lung illness, so machining it needs strict dust control. Never taste its compounds.