All practice pages/Interatomic theory/Elements

45Rh102.91

Element 45, a transition metal

Rhodium

One of the rarest and most expensive precious metals, working mostly out of sight inside car exhaust systems.

At a glance

Symbol
Rh
Atomic number
45
Average atomic mass
102.91
Group
9
Period
5
Family
transition metal
Electron configuration
[Kr] 4d⁸ 5s¹
Electronegativity
2.28
Common ions
Rh³⁺ in most compounds

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 5, group 9. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Rhodium has 45 electrons, one for every proton, so the atom carries no charge. Below are the same 45 electrons written two ways.

Simple form: electrons per shell

Rh
shell 12shell 28shell 318shell 416shell 51
Counting outward from the nucleus: 2, 8, 18, 16, 1. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁸ 5s¹

Short form: [Kr] 4d⁸ 5s¹, where [Kr] stands for the 36 electrons krypton already has.

That list runs by shell. In the order the subshells fill it reads [Kr] 5s¹ 4d⁸, because a subshell fills by its energy, not by its shell number.

4d⁸↑↓↑↓↑↓↑↑
5s¹↑
The boxes hold the electrons beyond [Kr]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 3 here is 3s² 3p⁶ 3d¹⁰, and 2 + 6 + 10 is 18.

Rhodium sits in period 5 and has 5 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 1 electron. Those are the ones rhodium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, rhodium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, silvery-white, highly reflective metal
Melting point
1964 °C
Boiling point
3695 °C
Density
12.4 g/cm³

Where it is found

Among the rarest elements in the crust, found with platinum in South Africa, which mines most of it, and in Russia.

Discovery and name

William Hyde Wollaston found it in 1803 in platinum ore from South America, shortly after he found palladium. He named it from the Greek rhodon, rose, for the pink color of its salts.

What it is used for

About 80% goes into catalytic converters, where it breaks down the nitrogen oxides in car exhaust. Rhodium also plates white gold jewelry for a bright finish, coats mirrors and reflectors, makes thermocouples for very hot furnaces, and catalyzes the production of several industrial chemicals.

In compounds

RhCl₃rhodium(III) chlorideRh₂O₃rhodium(III) oxideRhCl(P(C₆H₅)₃)₃Wilkinson's catalyst