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14Si28.09

Element 14, a metalloid

Silicon

The second most abundant element in the crust, the main ingredient of sand and rock, and the element computer chips are made from.

At a glance

Symbol
Si
Atomic number
14
Average atomic mass
28.09
Group
14
Period
3
Family
metalloid
Electron configuration
1s² 2s² 2p⁶ 3s² 3p², or [Ne] 3s² 3p²
Valence electrons
4
Electronegativity
1.90
Common ions
forms no simple ions; +4 in silicon dioxide and the silicates

On the table

Periodic table with Silicon highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 3, group 14. The other metalloids are tinted, and every cell opens its own article.

Electrons and bonding

Si

Four valence electrons like carbon, so silicon forms four covalent bonds. Unlike carbon it rarely bonds to itself in long chains; instead it links through oxygen, Si-O-Si, in quartz, glass and the silicate minerals.

Properties

State at 25 °C
solid
What it looks like
hard, brittle, blue-gray crystals with a metallic shine
Melting point
1414 °C
Boiling point
3265 °C
Density
2.33 g/cm³

Where it is found

About 28% of the crust by mass, second only to oxygen, but never free: it is in quartz sand, clay, granite and nearly every rock-forming mineral, bound to oxygen.

Discovery and name

Jöns Jacob Berzelius isolated it in 1824 by heating potassium fluorosilicate with potassium. The name comes from the Latin silex, flint, with the ending -on to match carbon and boron.

What it is used for

Ultra-pure silicon is the base of computer chips and most solar panels. Far more is used as sand and silicates in concrete, glass and ceramics. Silicon metal strengthens aluminum alloys, and silicones, polymers with a silicon-oxygen backbone, make sealants, bakeware, lubricants and medical implants.

In compounds

SiO₂silicon dioxide: quartz and sandSiCsilicon carbide, an abrasiveSiCl₄silicon tetrachlorideNa₂SiO₃sodium silicate, water glassSiH₄silane[(CH₃)₂SiO]ₙsilicone rubber