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76Os190.23

Element 76, a transition metal

Osmium

The densest element found in nature, named for the smell of its toxic oxide.

At a glance

Symbol
Os
Atomic number
76
Average atomic mass
190.23
Group
8
Period
6
Family
transition metal
Electron configuration
[Xe] 4f¹⁴ 5d⁶ 6s²
Electronegativity
2.20
Common ions
+4 most commonly; +8 in osmium tetroxide, OsO₄

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, group 8. The other transition metals are tinted, and every cell opens its own article.

Electrons and bonding

Osmium has 76 electrons, one for every proton, so the atom carries no charge. Below are the same 76 electrons written two ways.

Simple form: electrons per shell

Os
shell 12shell 28shell 318shell 432shell 514shell 62
Counting outward from the nucleus: 2, 8, 18, 32, 14, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d⁶ 6s²

Short form: [Xe] 4f¹⁴ 5d⁶ 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹⁴ 5d⁶, because a subshell fills by its energy, not by its shell number.

4f¹⁴↑↓↑↓↑↓↑↓↑↓↑↓↑↓
5d⁶↑↓↑↑↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹⁴, and 2 + 6 + 10 + 14 is 32.

Osmium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones osmium can lose, gain or share, so they are the ones that decide what it bonds with.

Like other transition metals, osmium loses its outer s electrons, and often some d electrons as well, to form positive ions, and it can form more than one kind.

Properties

State at 25 °C
solid
What it looks like
hard, brittle, bluish-white metal
Melting point
3033 °C
Boiling point
5012 °C
Density
22.6 g/cm³
Odd fact
the densest naturally occurring element, just ahead of iridium

Where it is found

Among the rarest elements in the crust, found with platinum in ores from South Africa and Russia and in natural osmium-iridium alloys.

Discovery and name

Smithson Tennant found it in 1803, together with iridium, in the black residue left after dissolving platinum ore in aqua regia. He named it from the Greek osme, smell, for the sharp odor of its volatile oxide.

What it is used for

Alloyed with iridium, its extreme hardness tipped fountain pen nibs, phonograph needles and instrument pivots. Osmium tetroxide stains fats for electron microscopes and was once used to reveal fingerprints.

In compounds

OsO₄osmium tetroxide, a microscopy stainOsO₂osmium dioxideK₂OsO₄potassium osmate

Handle with care

Osmium tetroxide is highly toxic and evaporates easily, and its vapor damages the eyes and lungs. Finely powdered osmium slowly forms it in air.