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68Er167.26

Element 68, a lanthanide

Erbium

A rare earth that amplifies the light carrying the internet under the oceans.

At a glance

Symbol
Er
Atomic number
68
Average atomic mass
167.26
Group
none; it sits in the lanthanide row below the table
Period
6
Family
lanthanide
Electron configuration
[Xe] 4f¹² 6s²
Electronegativity
1.24
Common ions
Er³⁺, pink in solution

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 6, in the lanthanide row set below the main table. The other lanthanides are tinted, and every cell opens its own article.

Electrons and bonding

Erbium has 68 electrons, one for every proton, so the atom carries no charge. Below are the same 68 electrons written two ways.

Simple form: electrons per shell

Er
shell 12shell 28shell 318shell 430shell 58shell 62
Counting outward from the nucleus: 2, 8, 18, 30, 8, 2. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹² 5s² 5p⁶ 6s²

Short form: [Xe] 4f¹² 6s², where [Xe] stands for the 54 electrons xenon already has.

That list runs by shell. In the order the subshells fill it reads [Xe] 6s² 4f¹², because a subshell fills by its energy, not by its shell number.

4f¹²↑↓↑↓↑↓↑↓↑↓↑↑
6s²↑↓
The boxes hold the electrons beyond [Xe]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 4 here is 4s² 4p⁶ 4d¹⁰ 4f¹², and 2 + 6 + 10 + 12 is 30.

Erbium sits in period 6 and has 6 shells. The period number counts the shells.

What that means for bonding

The outer shell holds 2 electrons. Those are the ones erbium can lose, gain or share, so they are the ones that decide what it bonds with.

Like the other lanthanides, it gives up three electrons to form the Er³⁺ ion in most of its compounds.

Properties

State at 25 °C
solid
What it looks like
soft, silvery metal
Melting point
1529 °C
Boiling point
2868 °C
Density
9.07 g/cm³

Where it is found

Found in xenotime, gadolinite and euxenite, and in the ion-adsorption clays of southern China.

Discovery and name

Carl Gustaf Mosander found it in 1843 in yttria from Ytterby, together with terbium, and it was named after the village.

What it is used for

Erbium-doped fiber amplifiers boost the light signals in long-distance fiber-optic cables, including those under the oceans, without converting them to electricity. Erbium also colors glass and cubic zirconia pink, and erbium lasers are used in skin treatments and dentistry.

In compounds

Er₂O₃erbium oxide, pinkErCl₃erbium chlorideErF₃erbium fluoride