All practice pages/Interatomic theory/Elements

9F19.00

Element 9, a halogen

Fluorine

The most electronegative element and the most reactive one, found in nature only as fluoride and never on its own.

In nature it is never aloneF₂Read about the molecule

At a glance

Symbol
F
Atomic number
9
Average atomic mass
19.00
Group
17
Period
2
Family
halogen
Electron configuration
1s² 2s² 2p⁵, or [He] 2s² 2p⁵
Valence electrons
7
Electronegativity
3.98, the highest of any element
Common ions
F⁻ (fluoride), as in NaF and CaF₂
Isotopes
¹⁹F only; every fluorine atom in nature is the same

On the table

Periodic table with Fluorine highlighted123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 2, group 17: the corner of the 7, where the top stroke turns down the halogen column. The other halogens are tinted, and every cell opens its own article.

Why it pairs up

F

Seven valence electrons, one short of eight. Two fluorine atoms share one pair, a single bond, and each has its octet.

Properties

State at 25 °C
gas
What it looks like
pale yellow gas made of F₂ molecules
Melting point
−219.6 °C
Boiling point
−188.1 °C
Density
1.70 g/L at 0 °C and 1 atm

Where it is found

About the thirteenth most common element in the crust, always as fluoride: in fluorite (CaF₂), in the fluorapatite of phosphate rock and of tooth enamel, and in cryolite (Na₃AlF₆). It is never free in nature, because F₂ reacts with almost everything it touches.

Discovery and name

The hardest element to isolate. Several chemists in the 1800s were poisoned trying, and some died. Henri Moissan finally made F₂ in 1886 by electrolysis of potassium fluoride dissolved in liquid hydrogen fluoride, and won the 1906 Nobel Prize for it. The name comes from fluorspar, from the Latin fluere, to flow: the mineral was added to ores to make them melt.

What it is used for

Fluoride in toothpaste and drinking water hardens tooth enamel. Fluorine compounds make non-stick Teflon coatings, refrigerants, the uranium hexafluoride used to enrich nuclear fuel, and about a fifth of modern medicines.

In compounds

HFhydrofluoric acid, etches glassNaFsodium fluoride, in toothpasteCaF₂fluorite(C₂F₄)ₙTeflonUF₆uranium hexafluorideSF₆sulfur hexafluoride