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9F19.00

Element 9, a halogen

Fluorine

The most electronegative element and the most reactive one, found in nature only as fluoride and never on its own.

In nature it is never aloneF₂Read about the molecule

At a glance

Symbol
F
Atomic number
9
Average atomic mass
19.00
Group
17
Period
2
Family
halogen
Electron configuration
1s² 2s² 2p⁵, or [He] 2s² 2p⁵
Valence electrons
7
Electronegativity
3.98, the highest of any element
Common ions
F⁻ (fluoride), as in NaF and CaF₂
Isotopes
¹⁹F only; every fluorine atom in nature is the same

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 2, group 17: the corner of the 7, where the top stroke turns down the halogen column. The other halogens are tinted, and every cell opens its own article.

Electrons and bonding

Fluorine has 9 electrons, one for every proton, so the atom carries no charge. Below are the same 9 electrons written two ways.

Simple form: electrons per shell

F
shell 12shell 27
Counting outward from the nucleus: 2, 7. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p⁵

Short form: [He] 2s² 2p⁵, where [He] stands for the 2 electrons helium already has.

2s²↑↓
2p⁵↑↓↑↓↑
The boxes hold the electrons beyond [He]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p⁵, and 2 + 5 is 7.

Fluorine sits in period 2 and has 2 shells. The period number counts the shells.

What that means for bonding

F

The outer shell holds 7 electrons. Those are the ones fluorine can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 17 means 7.

Seven valence electrons, one short of a full shell, so it gains one to form the F⁻ ion or shares one in a covalent bond.

Seven valence electrons, one short of eight. Two fluorine atoms share one pair, a single bond, and each has its octet.

Properties

State at 25 °C
gas
What it looks like
pale yellow gas made of F₂ molecules
Melting point
−219.6 °C
Boiling point
−188.1 °C
Density
1.70 g/L at 0 °C and 1 atm

Where it is found

About the thirteenth most common element in the crust, always as fluoride: in fluorite (CaF₂), in the fluorapatite of phosphate rock and of tooth enamel, and in cryolite (Na₃AlF₆). It is never free in nature, because F₂ reacts with almost everything it touches.

Discovery and name

The hardest element to isolate. Several chemists in the 1800s were poisoned trying, and some died. Henri Moissan finally made F₂ in 1886 by electrolysis of potassium fluoride dissolved in liquid hydrogen fluoride, and won the 1906 Nobel Prize for it. The name comes from fluorspar, from the Latin fluere, to flow: the mineral was added to ores to make them melt.

What it is used for

Fluoride in toothpaste and drinking water hardens tooth enamel. Fluorine compounds make non-stick Teflon coatings, refrigerants, the uranium hexafluoride used to enrich nuclear fuel, and about a fifth of modern medicines.

In compounds

HFhydrofluoric acid, etches glassNaFsodium fluoride, in toothpasteCaF₂fluorite(C₂F₄)ₙTeflonUF₆uranium hexafluorideSF₆sulfur hexafluoride