All practice pages/Interatomic theory/Elements

5B10.81

Element 5, a metalloid

Boron

A hard black metalloid that plants need, heat-proof glass depends on, and the strongest permanent magnets contain.

At a glance

Symbol
B
Atomic number
5
Average atomic mass
10.81
Group
13
Period
2
Family
metalloid
Electron configuration
1s² 2s² 2p¹, or [He] 2s² 2p¹
Valence electrons
3
Electronegativity
2.04
Common ions
forms no simple ions; +3 in compounds such as B₂O₃

On the table

123456789101112131415161718123456757-7189-103HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSrYZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg

Period 2, group 13. The other metalloids are tinted, and every cell opens its own article.

Electrons and bonding

Boron has 5 electrons, one for every proton, so the atom carries no charge. Below are the same 5 electrons written two ways.

Simple form: electrons per shell

B
shell 12shell 23
Counting outward from the nucleus: 2, 3. The outer shell is picked out.

Orbital form: electrons per subshell

1s² 2s² 2p¹

Short form: [He] 2s² 2p¹, where [He] stands for the 2 electrons helium already has.

2s²↑↓
2p¹↑
The boxes hold the electrons beyond [He]. Each box is one orbital and takes two electrons at most, spinning opposite ways. They spread out singly before they pair up.

How to read the two

The simple form counts electrons shell by shell. The orbital form says which subshell each one sits in: s holds 2, p holds 6, d holds 10 and f holds 14. Shell 2 here is 2s² 2p¹, and 2 + 1 is 3.

Boron sits in period 2 and has 2 shells. The period number counts the shells.

What that means for bonding

B

The outer shell holds 3 electrons. Those are the ones boron can lose, gain or share, so they are the ones that decide what it bonds with. For a main-group element the group number gives that count: group 13 means 3.

Three valence electrons. Boron is too small and holds its electrons too tightly to form B³⁺ ions, so it shares electrons in covalent bonds, often ending up with only six electrons around it instead of eight.

Properties

State at 25 °C
solid
What it looks like
hard, black, shiny metalloid
Melting point
2075 °C
Boiling point
4000 °C
Density
2.37 g/cm³

Where it is found

Never free in nature. It is mined as borate minerals such as borax and kernite, mostly in Turkey and in the Mojave Desert town of Boron, California. Plants need a trace of it to grow.

Discovery and name

Joseph Louis Gay-Lussac and Louis Jacques Thénard, and separately Humphry Davy, isolated impure boron in 1808. The name joins borax, from the Arabic buraq, with the ending of carbon, which boron resembles.

What it is used for

Borosilicate glass, the heat-resistant kind in lab glassware and oven dishes, uses a large share. Borax goes into detergents and homemade slime, and boric acid is a mild antiseptic and insecticide. Boron carbide is among the hardest materials made and goes into body armor. Boron-10 absorbs neutrons, so it helps control nuclear reactors, and boron is part of the neodymium magnets in motors and headphones.

In compounds

Na₂B₄O₇·10H₂OboraxH₃BO₃boric acidB₂O₃boron trioxide, in glassB₄Cboron carbide, body armorBNboron nitride, nearly as hard as diamondNd₂Fe₁₄Bneodymium magnet